二氧化氯催化氧化处理难降解废水技术的研究-环境工程专业论文.docx

摘要 二氧化氯作为一种水处理药剂因 其优良的性能己被广泛的应用 于水处理领域 ， 利用二氧化氯的强氧化性处理难降解废水是其在水处理中的主要用途之 一 。 本论文主要研究了二氧化氯催化氧化处理难降解废水技术中催化剂的制备，并 对二氧化氯化学氧化体系和 二氧化氯催化氧化体 系进行了经济技术比较 。实验结果 表明，催化制备最优条件为:催化剂焰烧温度 300 0C --- 350oC 、烧烧时间2h，浸渍 液浓度为 4% ，。单纯用二氧化氮化学氧化处理COD 为 3500mg/L 的酸性大红 GR 染料 废水时，最佳 pH 值为 6---8 ，二氧化氯投加量为1000mg/L 废水，反应 60min 后，COD 去除率可达 50%以上。 二氧化氯催化氧化处理酸性大红废水时，反应最佳 pH 值为 2 左右， C102 投加量为 800mg/L 废水，反应 45min---60min 时， COD 去除率可达 80% ， 氧化指数达 3.49 ，每公斤COD 去除氧化剂费用为 3. 72 元。 此外，本论文对催化剂寿命、再生方法与二氧化氯催化氧化机理进行了初步的 研究，并讨论了两种二氧化氯催化氧化的实用工艺。研究表明二氧化氯催化氧化法 是一种新型高效的处理难降解废水的技术，有着广阔的应用前景。 关键词二氧化氯催化氧化催化剂难降解废水 、、 Abstract As a kind of water treatment medicament ，chlorine dioxid e(Cl02) is wildly used in water treatment field because of ìts excellent functions. Utilizing i ts strong oxidizabì 1i ty to treat refractory wastewater is one of the primary uses of C102 in water treatment. The preparation of catalyst of Cl02 catalytic oxidation ，C102 chemical oxidation system and C102 cata1ytic oxidation system were studied in this oopaper. The results showed that 4% dip-liquid ，300 C 350 o o C and 2 hours of calcination were the best preparation conditions for catalysts. pH=6 8， lOOOmg CI0;.JL wastewater ， reacting 60min were the most efficient and economica l，when treating Acid Brilliant Scarlet GR dyestuff wastewater，the COD of which was 3500mg/L，by CIO:l chemìcal oxidation. The COD removal ratio exceeded 50%. When treating the wastewater by catalytic oxidation which was composed of CIO;! and special catalyst ， pH 均 2， 800mg CIO;/L wastewater ， reacting 45 60min were the most effícient and economícal. The COO removal ratio exceeded 80%，and the oxidation index was 3.49 (COO removal amount/ C102 used amount). The cost of oxidant removing lkg COO was ￥3. 72. Catalyst life，catalyst recovery and mechanism of C102 catalytic oxidation were elementarily developed . The study illuminated that C102 catalytic oxidation was an efficient method to treat refractory wastewater and it had a broad prospect. \ Keywords Chlorine Oi