催化裂化汽油萃取脱硫研究-应用化学专业论文.docxVIP

[HSO3-pMIM]pTSA 的脱硫率为 42.4%，油收率 94.6%；[HSO3-pPy]HSO4 的脱硫率为 34.0%，油收率 91.2%；[HSO3-pPy]pTSA 的脱硫率为 37.9%，油收率 93.6%。三级萃取脱硫实验：[HSO3-pMIM]HSO4 的脱硫率为 46.1%，油收率为 95.5%；[HSO3-pMIM]pTSA 的脱硫率为 53.0%，油收率 94.6%； [HSO3-pPy]HSO4 的脱硫率为 43.3%，油收率 96.2%；[HSO3-pPy]pTSA 的脱硫率为 45.8%，油收率 95.0%。 随着温度升高，脱硫率增加。通过本工艺，有效降低了 FCC 汽油的含硫量。 关键词： FCC 汽油 萃取脱硫 N-甲酰吗啉 磷酸三甲酯 离子液体 The Study on the Extractive Desulfurization of the FCC Gasoline Abstract To cut down the sulfur contents in the FCC gasoline effectively, the world are taking their steps in researching the non-hydrogen desulfurization technologies. Among them, more and more attention had paid to the solvent extraction and the newly developed ionic liquid(IL) extraction. We got satisfactory results from studying the extraction of the model and FCC gasolines using N-formoylmorpholine(NFM) 、 trimethylphophate(TMP) and ILs as extractants. In the experiment of the extractive desulfurization of the model and FCC gasoline by NFM upon optimized conditions, we came to the conclusion: the desulfurization ratio of model gasoline was 96.6%, in the conditions: ratio of solvent to oil 1:1, temperature 65℃, time 6min; The desulfurization ratio of FCC gasoline was 44.4%, in the conditions: ratio of solvent to oil 1:1, temperature 65℃, time 8min; The two and three stage desulfurization of FCC gasoline were 63.3% and 81.8%. There was not decrease in the desulfurization ratio when the solvent was recycled for 6 times. Then we made sure that NFM was an eximious solvent for the extract desulfurization of FCC gasoline. After optimizing the conditions in the experiment of continuous extractive distillating desulfurization of FCC gasoline by TMP, we came to the conclusion: operational load 4mL/min, reflux ratio 6:1, ratio of solvent to oil 2:1, ,the S contents of the FCC gasoline decreased from 2394.7ppm to 919.0ppm. In the paper we synthesized three ILs of phosphates: [MMIM]DMP, [EMIM]DEP, [BMIM]DBP and four Acid Functionalized ILs: [HSO3-pMIM]HSO4, [HSO3-pMIM]pT