复杂高硫渣中有价金属的分离工艺-中南大学学报.PDFVIP

复杂高硫渣中有价金属的分离工艺-中南大学学报.PDF

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复杂高硫渣中有价金属的分离工艺-中南大学学报

40 5 () Vol.40 No.5 2009 10 Journal of Central South University (Science and Technology) Oct. 2009 1 1 1, 2 (1. 410083 2. 335424) 95 0.5 h11׃1 2 98%6 150 g/L10׃165 96% 98%pH=0.8 pH=1.5 85.6%98%82%96% TF811 A 1672−7207(2009)05−1183−05 Separation and enrichment of valuable elements from complex high-sulfur slag 1 1 1, 2 LI Qian , ZHANG Bao , YANG Xing-wen (1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 2. Jiangxi Copper Company, Guixi 335424, China) Abstract: The separation and enrichment of valuable elements in the complex high-sulfur slag by oxygen-leaching from arsenic filter-cake were studied by the methods of re-desulfurization using kerosene, chloride-leaching, two-step hydrolysis. The effects of reaction time, temperature, mass ratio between the liquid and solid on leaching process were studied. The results show that the rate of desulfurization is 98% and the contents of Sb, Bi are enriched 6 times in the re-desulfurization slag when the temperature is 95 , the reaction time is 0.5 h and mass ratio between the liquid and solid is 11׃1 in the following two steps. In the chloride-leaching, the leaching rates of bismuth and antimony are 98% and 96%, respectively when the concentr

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