细乳液聚合法制备纳米TiO2丙烯酸酯共聚物的研究-毕业论文（设计）.docVIP

安徽大学 本科毕业论文 题　　目：细乳液聚合法制备纳米TiO2/丙烯酸酯共聚物的 研究 学生姓名：　　夏燕 学号：  细乳液聚合法制备纳米TiO2/丙烯酸酯共聚物的研究 摘要 本文首先使用甲基丙烯酸-3-三甲氧基硅烷(KH-570)对纳米TiO2粒子进行偶联处理，进一步通过细乳液聚合得到了内部包裹纳米TiO2粒子的核-壳型复合粒子。通过热重分析(TG)表征，表明纳米TiO2表面包覆约有9.13%~10.06%的K H-570；通过探讨乳化剂、助稳定剂用量与转化率的关系，结果显示：温度应控制在70℃，乳化剂用量为单体用量的2%，助乳化剂(HD)用量选为单体用量的3%时，可以得到稳定的胶粒粒径分布较窄的细乳液；通过吸水率、拉伸强度和热重分析测试，表明纳米TiO2可以提高聚合物的耐水性、耐候性和拉伸强度。 关键词：细乳液聚合；纳米TiO2；水性丙烯酸酯；KH-570；  Preparation of titanium dioxide/acrylate polymer nanocomposite particles via miniemulsion polymerization Abstract In this paper, nano-TiO2 particles was modified by 3-(trimethoxysilyl)- propyl- methacrylate(KH-570), and further the core-shell composite particles was preparation via miniemulsion polymerization. Thermogravimetric analysis (TG) characterization showed the encapsulation efficiency of nano-TiO2 was about 9.13% ~ 10.06% with the KH-570; and the relationships of the amount of emulsifier, stabilizer and the con- version were discussed,the results showed that: the temperature should be controlled at 70℃, when the content of emulsifier was 2% of the monomer and costabilizer(HD) was 3%, the particles can be stable with narrow particle size distribution; Besides, the water-absorbing ratio, pull extensor strength and TG tests showed that nano-TiO2 can increase the water resistance, weather resistance and tensile strength of the polymer. Key words: miniemulsion polymerization; nano-TiO2; acrylate polymer; 3-(trimeth- oxysilyl)propyl methacrylate  目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc231298504 第一章 前言 PAGEREF _Toc231298504 \h 1 HYPERLINK \l _Toc231298505 1.1 水性丙烯酸酯树脂的研究进展 PAGEREF _Toc231298505 \h 1 HYPERLINK \l _Toc231298506 1.2 水性丙烯酸酯纳米复合物的进展 PAGEREF _Toc231298506 \h 1 HYPERLINK \l _Toc231298507 1.3 聚合方法的选择 PAGEREF _Toc231298507 \h 2 HYPERLINK \l _Toc231298508 1.4 本实验方法的简介 PAGEREF _Toc231298508 \h 3 HYPERLINK \l _Toc231298509 1.4.1 实验步骤简介 PAGEREF _Toc231298509 \h 3 HYPERLINK \l _Toc231298510 1.4.2 反应机理 PAGEREF _Toc231298510 \h 3