炔基官能团化茂金属化合物的合成、催化性能与反应性的-研究.pdf

中文摘要 部分具有非锯马几何构型，存在一个亚桥连的羰基。 和{r／5-[1，2…RE Ru3(CO)12在苯中加热回流反应，则得到三核钌杂环化合物 关键词：炔基官能团化；二茂钛锆化合物：乙烯聚合；钌杂环戊二烯；亚桥连 的羰基． Abstract Abstract three Thisdissertationcontains of aspects：Thesynthesis titanoceneandzirconocene and廿1eir catalytic complexes ethylenepolymerization reactionsof zirconocene with behaviors，the alkynyl-functionalizedcomplexes of ferroceneand synthesis ruthenocene Ru3(CO)12，the alkynyl—functionalized andthereactionsof ferrocene with complexes alkynyl-funcfionalizedcomplexes Ru3(CO)12． 1．Aseriesof alkynyl—functionalized‘cyclopentadienes and 4；2，n=2)，PhC2(C5Ph2H3)(3)weredesigned andtransmetallationwith and the deprotonation TiCh‘2Tl圮ZrCh yielded Cp’ZrCl3 titalloceneand zirconocene alkyne-functionalized complexes{矿- [IPMe (7)，Ph(8)]， Cp’{r／5-[C掣Me4(C-=CPh)]}ZrCl2(9) and withMAO their for werestudied．Theresults catalytic ethylene properties polymerization indicatedthatthezirconocene 6-11showed activitiesthanthe complexes higher fitanocene 5；the and complex unsymmetricalphenylcthynyldimethyldiphenyl zirconocene10and11showed activitiesthan cyclopentadienylcomplexes