聚乙烯共聚物的制备-SitesDuke.PDF

聚乙烯共聚物的制备 徐志贤, 李伯耿, 介素云 (湖南理工大学材料科学系，长沙 561231) Abstract： Catalyzed by a phenoxycyclopentylimine ligated zirconium complex/dried methylaluminoxane (dMAO) system at 40℃ under 1 atm of ethylene pressure, linear vinyl-terminated polyethylene (PE-ene) with nearly 100% of end-functionality was produced via ethylene polymerization. With high efficiency, hydroxyl-terminated polyethylene (PE-OH) was subsequently prepared via the radical initiated thiol-ene click chemistry bet