富氢气中CO氧化脱除研究.PDF

第 19 卷 第 6 期 化　学　进　展 Vol. 19 No. 6 2007 年 6 月 PROGRESS IN CHEMISTRY 　June , 2007 富氢气中 CO 氧化脱除研究 1 1 2 周桂林 　谢红梅 　邱发礼 ( 1 重庆工商大学 环境与生物工程学院 　重庆 400067 ;2 中国科学院成都有机化学研究所 　成都 610041) ( ) 摘　要 　富氢气中少量的 CO 会导致燃料电池电极中毒 ,质子交换膜燃料电池 PEMFC 的发展急需解 决该问题。目前以催化氧化脱除富氢气中少量 CO 是较理想的方式。本文概述了富氢气中 CO 选择性氧化 脱除的研究进展 ,并展望了今后研究的方向及应用前景。 关键词 　富氢气 　一氧化碳 　选择性氧化 ( ) 中图分类号: TQ0317 ; TQ1162 　文献标识码 : A 　文章编号 : 1005281X 2007 Carbon Monoxide Oxidation Removal in HydrogenRich Gas 1 1 2 Zhou Guilin 　Xie Hongmei 　Qiu Fali ( 1College of Environmental and Biological Engineering , Chongqing Technology and Business University , Chongqing 400067 , China ;2Chengdu Institute of Organic Chemistry , Chinese Academy of Sciences , Chengdu 610041 , China) Abstract 　The electrode of proton exchange membrane fuel cells (PEMFC) can be poisoned because of the strong adsorption of CO , which is need to be resolved for the development of PEMFC urgently. In fact , among the various available methods for CO removal from hydrogenrich gas atmospheres , the selective catalytic oxidation of CO had been regarded as the most straightforward , simpler and cost effective ones. The studies on CO selective oxidation are reviewed , future prospects of researchs and applications of the catalytic system are presented. Key words 　hydrogenrich gas ;