基于电导率法对老化沥青胶体稳定性的研究1.PDF

基于电导率法对老化沥青胶体稳定性的研究1 曹芯芯，曹雪娟 （重庆交通大学，重庆400074） 摘要： 沥青胶体不稳定系数能够较好的反映沥青老化过程中胶体性能变化，计算胶体 不稳定系数需要对沥青进行四组分分离，四组分实验存在耗时长、重复性差、准确性低的缺 点。研究采用电导率法对沥青老化过程中胶体稳定性的变化进行分析，并通过胶凝渗透色谱 （GPC）对沥青老化进行微观表征。研究发现质量分数电导率评价沥青胶体稳定性是可行的， 沥青随着老化程度的加深，能够容纳正庚烷的含量减少，胶体稳定性降低。GPC 实验结果 表明沥青老化过程中大分子 （LMS ）、中分子 （MMS ）和小分子 （SMS）变化各不相同， 而LMS 含量与胶体稳定系数、三大指标具有较高的相关性，LMS 的增加是造成沥青老化胶 体稳定性降低的主要原因。 关键词： 沥青老化、胶体稳定性、电导率、凝胶渗透色谱 中图分类号：U414 The investigation of colloidal stability of aged asphaltin based on asphalt conductivity test Xinxin Cao ，Xuejuan Cao （ Chongqing Jiaotong University，Chongqing 400074 ） Abstract The unstable colloidal coefficient of asphalt can reflect the change of colloidal property in asphalt aging, asphalt four components analysis is necessary to calculate the unstable colloidal coefficient, the four components experiment has the disadvantages of taking long time, poor repeatability and low accuracy. In this paper, the change of the colloidal stability in asphalt aging was analyzed by mass fraction conductivity, and asphalt is microscopically characterized by gel permeation chromatography(GPC). It is found that the mass fraction conductivity is feasible to evaluate the colloidal stability of asphalt. with the increase of aging degree, the content of n-heptane is reduced and the colloidal stability decreasing. The experimental results shows that the changes of large molecules size (LMS), middle molecules size (MMS) and small molecules size (SMS) are various in asphalt aging, the LMS content has a high correlation with the coefficient of colloidal stability and the three indexes of asphalt, the increase of LMS is the main reason for the decrease of the colloidal stability of asphalt in aging. 基金项目：重庆创新基金2017