磁性离子液体中导电聚合物多壁碳纳米管复合材料的制备及性质分析-有机化学专业论文.docx

磁性离子液体中导电聚合物/ 磁性离子液体中导电聚合物/多壁碳纳米管复合材料的制备及性质研究 IV IV The electrochemical activity of the composite was excellent. The thermal stability of PEDOT/MWCNTs nanocomposites with 10% MWCNTs was obviously improved compared with that of PEDOT. The PEDOT/MWCNTs nanocomposite was prepared via ultrasound. The structure and morphology were characterized by FT-IR and SEM. The electrochemical property was investigated by cyclic voltammetry. (3) The PPy/MWCNTs nanocomposites with different MWCNTs content were synthesized via ball mill in MIL. The structure and morphology of the PPy/MWCNTs nanocomposites were characterized by FT-IR, UV- Vis, SEM and TEM. The conductivity of the composites was measured by four-point probe sheet resistance measurement. The electrochemical properties of the PPy/MWCNTs nanocomposites were investigated by cyclic voltammetry and Chronopotentiometry in 1 mol/L KCl.The thermal stability was analysed by TGA. The results show ed that PPy/MWCNTs nanocomposites with core-shell structure were Prepared via ball mill. The conductivity of PPy/MWCNTs nanocomposites was more improved compared with that of ppy. The PPy/MWCNTs nanocomposites had the excellent electrochemical activity. PPy/MWCNTs(20% MWCNTs ) had the best electrochemical energy storage properties, the specific capacitance was up to 186 F /g, which was greatly improved compared with that of ppy. The thermal stability of PPy/MWCNTs(20% MWCNTs)was obviously improved compared with that of PPy. Key words: Poly(3,4-ethylenedioxythiophene), Polypyrrole, Magnetic ionic liquid, MWCNTs, Nanocomposite VIII VIII 图、表清单 图 1.1 常见导电聚合物........................................................................................................... 1 图 1.2 典型的金属、半导体、绝缘体的导电率的范围 ............................................................. 2 图 1.3 聚乙炔的双极化子与孤子的结构示意图........................................................................ 3 图 1.4 聚 3, 4-乙撑二氧噻吩聚合过程......................................................................