磁性纳米Fe3O4@ZrO(OH)2的合成及对水中氟和砷的吸附性能研究环境工程专业论文.docx

II II Abstract Fluoride ions and arsenic has a potential hazard to plants, animals and human beings，and the research for removing fluoride ions and arsenic from water has become a hot point to the environmental science. In this paper, a new type of magnetic nanoparticle Fe3O4@ZrO(OH)2 was performed with Fe3O4 coated with zirconium oxyhydrate in order to remove high concentration fluoride ions and high As(III/V) from aqueous solutions. This absorbents were also been characterized. The adsorption efficiency and the influences of various factors were investigated，such as adsorption capacity, reaction time, pH values, co-existing anions, deabsorption and removal efficiency. The research results showed that: This magnetic nanoparticle Fe3O4@ZrO(OH)2 can removal of fluoride ions quickly. The adsorption isotherm could be well fitted using the Langmuir and Freundlich model. The maximum adsorption capacity of Fe3O4@ZrO(OH)2 to fluoride ions was 188.68 mg/g. The adsorption process of the fluoride ions is spontaneous nature. With increasing initial solution pH, the adsorption capacity of fluoride ions was always decreased. Fe3O4@ZrO(OH)2 could use more than four times after it was desorbed. The maximum adsorption capacity of Fe3O4@ZrO(OH)2 to As(III) and As(V) calculated by Langmuir equation was 188.68 mg/g and 108.70 mg/g, respectively. The adsorption isotherm could be well fitted using the Langmuir and Freundlich model. The effects of adsorption time followed a pseudo-second-order rate equation can get contact time to As(III/V) of 10min was adequate to reach equilibrium. The adsorption process of the As(III) is spontaneous nature. With increasing initial solution pH, the adsorption capacity of As(III) was first increased and then decreased, while As(V) was always decreased. Fe3O4@ZrO(OH)2 could use more than four times after it was desorbed. When exist fluoride ions and As(III/V) simultaneously in solution, the maximum adsorption capacity of Fe3O4@ZrO(OH)