纯镁薄壁管冷拉拔工艺及模拟体液中纯镁腐蚀行为研究-材料加工工程专业论文.docx

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 万方数据 万方数据 Abstract Magnesium is becoming a popular research subject in the Biomedical Materials Field because of its outstanding biological properties. First, Mg has HYPERLINK /dict_result.aspx?searchword=%e7%94%9f%e7%89%a9%e7%9b%b8%e5%ae%b9%e6%80%a7amp;tjType=sentenceamp;styleamp;t=biocompatibility biocompatibility and degradability .Second, the Young’s modulus of Mg is close to human body’s bones. However, Mg is difficult to deformation at room temperature and is corroded rapidly in chloride containing solution, such as the human body fluid. Therefore ，if want to prepare magnesium thin-wall tube used in the Biomedical Materials Field, it is necessary to research preparation process and Corrosion Resistance of the tube. In this paper, certain wall thickness of pure magnesium thin-walled tube was prepared by cold drawing process combined with intermediate annealing. Changes of tissue preparation and deformation mechanism of the tube have been analyzed. Then, the factors relating the corrosion of tubes such as the grain size, texture, twin and corrosion medium were studied .At last , The corrosion behavior of pure magnesium thin-walled tube have been research by Immersion test. Magnesium thin-wall tube was prepared by 35 times cold drawing combined with 4 times intermediate annealing. The cumulative deformation scale is 0.7395. Grain is elongated along the drawing direction, some of the grain is refined. The drawing deformation mechanism of Mg tube was based on dislocations slip, twining and grain coordination mechanism. The effects of grain size, texture, twin and corrosion medium on corrosion resistance were studied by electrochemical tests and immersion test. It was found that the effect of grain size on corrosion performance exist threshold, beyond this threshold, corrosion resistance will be worsen. The surface of Mg occurred pitting corrosion when the grain size is small, the filiform corrosion occurred as the increases of th