分子筛水浆料吸收CO2传质强化的研究-化学工程专业论文.docx

摘 要 难溶气体吸收的传质强化是化 工研究中的一个重要课题，特别是第 三分散相对气液传质过程的强 化近年来广受关注。本文研究了 4 种不同硅 铝 比（ SiO2/Al2O3=100、 120、 150、 360）分 子筛在不同工况条件下对 CO2 吸收的增强作用，并建立了一 维和三维非均相理论模型。 采用恒温搅拌釜研究了硅铝比、初始压力、 CO2 气相分压、固含率等 因素对 CO2 吸收过程的影响。结果表明：随着硅铝比的增加，增 强因子逐 渐增大；而随着初始压力、 CO2 分压、转速的增大，增强因子逐渐减 小； 随着固含率的增加，增强因子先迅速增 大，而后逐渐趋于恒定值。另外 ， 实验还研究了超声对增强因子的影响，对 分子筛浆料超声后，分子筛强化 传质的效果增强。 根据经典传输机理建立了一个一维非均 相传质模型 ，该模型平均增 强 因子的计算值与实验结果吻合良好。同时，还 建立了一个三维非均相传质 模型，考 察了多维条件下各因素对增强因子的影响，并计算了平均增强因 子和瞬时增强因子 。该模型计 算的平均增强因子和瞬时增强因子相比一维 模型更加准确，表明三维模型更加合理。 关键词： 吸收，气液传质，分子筛，增强因子，传质模型 ABSTRACT The enhancement of mass transfer of lower solubility gas is an important project for chemical process research, especially introducing a third dispersed phase to improve gas-liquid mass transfer drew wide attention in recent years. The intensifications of four different SiO2/Al2O3 ratio zeolites to CO2 absorption under different conditions were experimentally investigated. And a one dimensional (1-D) and a three dimensional (3-D) heterogeneous mass transfer models were proposed to depict the intensification of mass transfer in CO2 absorption. The experiments were carried out in a thermostatic stirred tank, the effect of SiO2/Al2O3 ratios, initial pressure, CO2 partial pressure, solid loading on CO2 absorption were investigated, respectively. The results indicated that the enhancement factor increased with the increase of SiO2/Al2O3 ratios, but reduced with the increase of initial pressure, CO2 partial pressure and stirring speed. When solid loading increased, the enhancement factor increased sharply at first and then gradually leveled off to a constant value. Furthermore, the effect of ultrasound to enhancement factor was also investigated, the intensification of mass transfer by zeolite was improved when the slurry was ultrasounded. A 1-D heterogeneous model was proposed based on the classical “shuttle” mechanism, the calculated average enhancement factor by this model under different conditions agreed well