磁性纳米材料的制备及性能分析-高分子化学与物理专业论文.docx

Abs Abstract 磁性纳米材料的制备及性能研究 磁性纳米材料的制备及性能研究 PAGE PAGE III IV IV Abstract In this dissertation, magnetite nanoparticles have been prepared by precipitation from partially reduced Fe3+ using a green synthesis method. Besides, electrostatic interaction, in-situ reduction etc., have been used to synthesize core-shell materials such as Fe3O4@Au, Fe3O4@TiO2. The properties and formation mechanisms of products have also been investigated. The main contents are summarized as follows: Superparamagnetic Fe3O4 nanoparticles were synthesized with a simple and rapid method by precipitation from partially reduced Fe3+ at low temperature, without any additional agent and the protection of inert gas. The results shows that with the rise in temperature, the diameter of Fe3O4 nanoparticles gradually increased with better dispersibility and high crystal type. Also, the surface of Fe3O4 nanoparticles were modified by biomolecule at higher temperature. Furthermore, the effect of stirring speed and concentration of ammonia on Fe3O4 nanoparticles were investigated. The best stirring speed is at 2500r/min, and ammonia is act as precipitating agent and dispersing agent. This study provided a simply and feasible way for preparation of other nano-materials. Biocompatible L-homocysteine modified Fe3O4@Au nanoparticles were hierarchicaly synthesized. At first, superparamagnetic Fe3O4 nanoparticles with well dispersibility were synthesized. Subsequently, Fe3O4@Au core-shell structure was prepared by an in-situ reduction in the presence of Au3+ and ascorbic acid at pH 4.5 and the average thickness of gold nanosheets is about 10nm. Last, Linking L-homocysteine molecules to Au shell. It was found that the aggregation of the nanoparticles was governed by the intermolecular interaction between the homocysteine molecules and also the pH of the solution. The Fe(2p3/2) peak shifted slightly from 708.2eV to 711.2eV due to the coating of Au atoms on its surface. This suggests a strong el