超重力环境下脱除气体中硫化氢的基础研究无机化学专业论文.docxVIP

中北大学学位论文 中北大学学位论文 理效果最好，其脱硫率可达到 99%以上。 论文根据脱硫液对硫化氢气体的吸收效果与气液比的关系，使用 MATLAB 高级语 言拟合出脱硫液对硫化氢气体的吸收效果与气液比关系曲线的表达式，并对其积分，得 出在超重力环境下脱硫液的工作硫容可达 0.4g/L。 与传统工艺相比，在保持脱硫效果不变的条件下，超重力环境下以 PDS 为催化剂 的脱硫液的工作硫容从 0.2g/L 提高到 0.4g/L，脱硫吸收过程的液气比降低至原来的 1/4～ 1/2，单位时间内液体的循环量降低到原来的 1/10。 论文脱硫富液的再生实验部分首先通过正交实验考察了再生时间，进气量，进液量 等因素对再生效果的影响。以脱硫液中可溶性硫化物和脱硫催化剂 PDS 含量的变化来 对再生效果进行表征。实验结果表明：再生塔内鼓入的空气量对脱硫富液中可溶性硫化 物的催化氧化效率影响最大，而再生塔内脱硫液的进液量对催化剂 PDS 的再生效果影 响最大。综合各因素，本实验中脱硫富液再生的最佳条件：再生时间为 30min，进气量 为 2m3/h，进液量为 50L/h，此时硫化物的催化氧化再生效率为 72%，脱硫催化剂 PDS 的再生效率为 97%。 关键词： 超重力技术，硫化氢，催化氧化，脱硫，再生 The basic study on desulfurization under the condition of high gravity Abstract The development and research on the technologies of desulfurization from industrial gas were reviewed in this paper, and all of the desulfurization technologies can be divided into dry, wet desulfurization and biological desulfurization. Among all of the technologies, the dry desulfurization which is the removal of sulfide compounds by solid sorbent is mainly suitable for processing with low hydrogen sulfide gas, especially for fine desulfurization. Biological desulfurization is to use the microorganism which exists on the porous filter in the form of bio-film to metabolize hydrogen sulfide, but there are issues such as the slow rate of desulfurization, unstable removal efficiency and so on. The wet desulfurization includes wet oxidation desulfurization and wet absorption desulfurization. The wet absorption method is to release the absorbed H2S by the regeneration system to Claus system, and then converted into sulfur, the solution could be recycle using. Wet oxidation could directly convert the H2S absorbed into the solution into sulfur, and then the regeneration solution could recycle using again after the separation. Because of the directly oxidation H2S into sulfur, and avoiding the secondary pollution, it is widely used. The traditional main equipment for the desulfurization process is the packed tower, due to being operated in normal gravi