磁性纳米材料的制备及其对水体中微量污染物的吸附性能分析-环境工程专业论文.docx

II II 子；Hg(II)；染料；细菌吸附 PAGE PAGE III Abstract Water pollution is one of the most serious problems in the current water crisis, so the treatment of water pollution cannot be delayed. Though adsorption is a high-efficient, simple technique among the methods of controlling water pollution and could be apply widely, the separation and recycle of the adsorbent are difficult. The emergence of magnetic materials, which makes the recycle of adsorbent possible, injects new vitality into the development of the adsorption technique. Due to the magnetism and large surface area of Fe3O4, these magnetic materials gained widespread attention in the areas of the development of new adsorbent materials. According to the characteristics of common pollutants in water environment, three magnetic adsorbents were designed and synthesized, and their adsorption properties were also discussed in the present paper. So far many researches on the preparation of amine-functionalized magnetite particles by two steps have been reported, of which the preparation processes were complicated and the quantities of consumed detergents were high. Therefore, a facile and efficient one-pot method was applied in this paper to prepare Fe3O4 -NH2 nanoparticles using FeCl3·6H2O as the sole Fe source. The as-prepared material was then applied to remove the Hg (II) ions in the water. Compared with Fe3O4 that were also synthesized by one-pot method, Fe3O4-NH2 nanoparticles showed more excellent adsorption capacity in spite of their smaller surface area. Batch laboratory techniques were utilized to study the equilibrium of Hg (II) adsorption on nanosized Fe3O4-NH2. Equailibration time of the adsorption was estimated as 30 h at optimized pH of 7. The pseudo-second order kinetic model and Langmuir model appeared to be appropriate for describing the equilibrium conditions, and the maximum adsorption capacity reached 29.02 mg/g. In addition, the adsorption capacity reduced a little after 3 recycle. Ethylenediami