磁控溅射制备锡薄膜锂离子电池负极材料及其电化学性能分析-分析化学专业论文.docx

I I 磁控溅射制备锡薄膜锂离子电池负极材料及其电化学性能研究 中文摘要 中文摘要 锡基负极材料相比其它负极材料而言具有诸多优点，例如高容量(992 mAh g-1)、对电解液选择限制少等，引起了人们的广泛关注。 本文采用磁控溅射法合成了 Sn 金属薄膜，以此材料为锂离子电池负极，研究 了其电化学性能。通过调节磁控溅射时间，制备了由不同粒径 Sn 粒子组成的 Sn 薄膜材料。研究表明：磁控溅射时间为 10 分钟，薄膜表面 Sn 粒径为 25 - 150 nm 的 Sn 薄膜负极材料性能最佳，经过 50 次循环后，放电容量仍能保持在 420 mAh g-1。 为进一步研究锡在充放电过程中的体积过程，对循环不同圈数后的电池进行 拆解，采用扫描电子显微镜(SEM)技术揭示了 Sn 在充放电过程中经历膨胀、破裂 和粉化的体积变化过程，使其导电性能下降，电池循环性能也显著降低。为改善 导电性能，在循环 30 圈后的电极表面磁控溅射一层导电体(铜或碳)，对电极进行 改性。电池性能结果显示：引入导电体(铜或碳)后，电池的电化学性能得到较大提 高，循环 50 次后，放电容量分别为 520 mAhg-1(铜)、550 mAhg-1(碳)。 采用煅烧法制备了 Sn-Cu 合金。实验结果表明：制备得到的 Sn-Cu 合金为 Cu3Sn 相，其中煅烧条件为 200℃，2 小时的样品循环性能最佳，充放电 50 圈后容量仍 能保持 467 mAhg-1，高于原磁控溅射法制备的锡薄膜循环 50 圈之后的容量(420 mAhg-1)。 关键词：锡，Sn-Cu 合金，磁控溅射，导电性，锂离子电池。 作 者：吴梦 指导教师：周群 II II 英文摘要 磁控溅射制备锡薄膜锂离子电池负极材料及其电化学性能研究 Fabrication of Sn film via magnetron sputtering towards understanding electrochemical behavior in lithium-ion battery applications Abstract Tin (Sn) attracts considerable attention as an anode material for lithium-ion batteries due to its high theoretical capacity. In the present work, Sn thin film composed of numerous continuous Sn particles was prepared on a copper foil via magnetron sputtering. We have investigated the electrochemical properties of the Sn thin film, as anode electrode in lithium ion batteries. In this thesis, Sn thin films with different size of Sn particles were prepared by adjusting the time of sputtering. Sn thin film composed of numberous Sn particles (ranging from 25 to 200 nm) exhibited the best electrochemical performance with a discharge capacity of 420 mAh g-1 after 50 cycles. To understand the process of Sn volume change, the process of Sn volume change was investigated via SEM. Modifying the surface of Sn electrode with a conductor was achieved after a thin conductive layer (copper or carbon) was sputtered onto the Sn electrode after cycling 30 times. The Sn-MS-Cu and Sn-MS-C elec-trodes showed an increase in electrochemical performance, the modifying electrodes delivered high capacity of 520 mAh g-1