纯镁超声微弧氧化-多种复合处理生物涂层的研究-材料学专业论文.docx

佳木斯 佳木斯大学硕士学位论文 万方数据 万方数据 Abstract Magnesium and magnesium alloys were limited in the clinical application as biodegradable bone fixation materials because they were degraded quickly. A new method named pure magnesium ultrasound micro-arc oxidation(UMAO) dipping composite treatment was put forward that process different composite treatments included HF-Na2SiO3, HF-silica sol (CSG) and NaOH-silane coupling agent (SCA) after UMAO treating on pure magnesium in silicate electrolyte to regulate the rate of degradation and bioactivity of pure magnesium UMAO biological coating, Search Engine Marketing(SEM), Energy Dispersive Spectrometry(EDAX), X-ray diffraction (XRD), the contact angle tester, the scratch tester, the electrochemical workstation and the pin-disc friction and wear tester were investigated to analyze the microstructure, phase composition, the phase structure, the contact angle, adhesion force, electrochemical corrosion and friction coefficient of the UMAO-composite coatings on pure magnesium. The technology and the treatment mechanism of different UMAO-composite coating were discussed. The formation of the bone-like apatite on coatings were analyzed after immersed in simulated body fluid. The surface pores of the dense biological coating on pure magnesium were filled by composite after UMAO-composite treatment. The phase structure of UMAO coating was MgO, MgSiO3, SiO2 and MgF2. The adhesion force of single UMAO coating was 4.6N while that increaseed to 4.8N-7.8N after combined treatment. The friction coefficient of single UMAO coating was 1.1 while that reduced to 0.8-0.35 after composite treatment. The MAO-HF-CSG coating had the best adhesion force and wear resistance whose adhesion force reached to 7.8N and friction coefficient reduced to 0.35. The corrosion resistance of the different treatment coatings was superior to single UMAO coating. The corrosion resistance of UMAO-NaOH (3mol/L)-SCA coating was the best whose corrosion potential (Ecorr) improved 7