《钛硅分子筛的研究进展》课件.pptVIP

钛硅分子筛的研究进展 指 导 老 师 徐 杰 博 士 生 高 肖 汉 2004.10.2 Outline Background and application of the Titanosilicate Preparation and characterization of the Tianosilicate Structure and mechanism of the Tianosilicate Background of TS-1 In1967，the zeolite containing TiⅣ was mentioned in US 3329480 In1983， the preparation and characterization of TS-1 was reported by Taramasso (Italy) in US 4410501 Later , the preparation of Ti-ZSM-11, Ti-MCM-41 Ti-HMS and Ti-MSU were reported. Speciality of TS-1 Reacted under mild condition (0℃-100℃, air pressure) Remarkable shape-selectivity Friendly Evaluation of TS-1 The selective oxidation of organic substrates by H2O2 in the presence of TS-1 is an interesting area of high potentiality for development of new environmentally friendly technologies The route of preparing TS -1 Gas-solid isomorphous replacement method In-Situ embedded method Hydrothermal method Hydrothermal method Surroundings of Ti Mechanism 1 of TS-1 Mechanism 2 of TS-1 * * seminarⅡ The pore of TS-1 is about 0.5nm The advent of TS-1 represented the next major innovation enabling shape-selective oxidations to be carried out in industrial scale Notari. B., Adv. Catal. 41 (1996) 253 Keshavaraja. A.,et al.,J. Catal. 157 (1995) 501 TS-1 + 30 %H2O2 OH OH OH OH + OH OH + NH3 O NOH R O R R R’ O RR’CHOH RR’CH2 RR’CHOH Already Industrialized (10,000t/a) Already Industrialized （12,000t/a) promising industrialized By-product: only water !!! Application of TS-1 Ti Source: TEOT TPOT TBOT TiCl3 TiCl4 Amorphous TiO2 Template: TPA+ TBP+/TEP+ TBA+/TEA+ TPA+/TEA+ Mineralising agent: OH- NH4+ Methylamine Hexanedimine Si Source: TEOS Fumed silica Colloidal silica Amorphous SiO2 混合液 Crystallized, filtrated, washed, dried, calcined TS-1 N+ OH N+ OH Si O O O O Ti O O Si O Solution of