彩棉的结构及热性能(I)形态结构与红外光谱表征.docVIP

天然彩棉与木棉的结构及热性能（I）:形态结构与红外光谱表征 采用化学分析、SEM、红外光谱研究了棕棉、绿棉（又分为浅绿和绿色棉）和木棉纤维的化学组成、 氢键结构和微观结构的差异，并与白棉纤维进行Y比较。研究表明绿棉屮冇较高的蜡质含《，主耍为脂肪 酸，而棕棉的蜡质含觉较低主耍为脂肪醉。木棉纤维具冇最高的木质素和半纤维素（木聚糖）含录，但其 木聚糖有异常髙的取代度。相比深绿棉，浅绿棉的软木脂含量更高，高的软木脂含量会导致浅绿棉中 06-H -0桥键的缺失，影响氢键结构的完整性。SEM观察显示天然彩棉中深绿棉其有较大的胞宽壁厚的比 值，其次为浅绿棉。因为较高的非纤维索成分，木棉和深绿棉没宥观察到纤维索的微纤结构，而浅绿棉只 冇小?的微纤显露在表面，棕棉纤维的表面分布看较宽的微纤构造。 关键词：彩棉；木棉；形态结构；红外光谱 Structure and thermal properties of natural colored cotton and bombax cotton (I): morphological structure and FTIR characterization Abstract: Chemical compositions, hydrogen bond configuration，and microstructure of bombax, laurel green, bottle green，and brown cotton were investigated by chemical analysis, SEM, IR spectra. The results showed that a higher content of waxiness mostly composed of fatty acid existed in green cotton, whereas brown cotton has a lower content of waxiness, which was mostly composed of fatty alcohol. Bombax cotton has the greatest content of lignin and xylan，but the xylan in bombax cotton was substituted with significantly high levels of acetyl groups. The higher suberin content in laurel green cotton compared with bottle green cotton results in the lack of O6-H…Obridge in the fiber formation. Observation of SEM showed that bottle green cotton has the greater ratio of the width of the cell and the thickness of the wall among natural cottons, and the next is laurel green cotton. Cellulose microfibrillar configurations can’t be observed in bombax and bottle green cotton with more noncellulose component，and laurel green cotton only has a few of cellulose microfibrillar on its surface. The wider microfibrillar configuration also can be observed on the surface of brown cotton. Key words: colored cotton; bombax cotton; morphological structure; FTIR 天然彩棉因无需染色、绿色环保的特征正受到人们的关注。此外，木棉纤维以其独特的 薄壁大中空结构在保暖性方血具有独特优势，已广泛地运用于枕头、填絮被、羽绒等填充料。 彩棉和木棉的独特的性能和它们的化学组成、微观结构有着密切的关联，Elesini等的研宄显 示相比白棉，绿棉中有更高的软木脂含量，这会导致导致O6-H-O桥键的缺失［1］; Hori等人 详细地表征了木棉屮木质素的结构，并认为木棉纤维有较好的亲油性［2］。虽然彩棉和木棉的 运用越来越受到重视，总的来说有关它们结构和性能的系统研究仍