电光激励对掺稀土镧代锆钛酸铅陶瓷发光性能的影响-光学专业论文.docxVIP

Abs Abstract -II- -II- Abstract Since the advent of the ruby laser, lasers and laser technologies advanced rapidly. It is a milestone in laser field that the advent of full solid state lasers, because solid state lasers have more advatages over their gas and liquid counterparts, including a wide range working media, small volume and light mass. Until now, searching for an ideal laser material still plays a dominant role in the development of laser technique. Among the solid laser materials, lanthanum lead zirconate titanate (PLZT) ceramics attract braod attention because of their highly transparency, wide optical window from 400 nm to 6 μm, low cost, and their electro-optic, piezoelectric, pyroelectric and photochromatic effects. Rare earth doped PLZT ceramics exhibited excellent spectral characteristic, which is sensitive to external electric field and radiation (or illumination). Therefore, multifunctional and tunable solid microlaser can be developed based on these effects. In this thesis, electric field and ultrovoilet light induced changes of upconversion, absorption and fluorescence spectrum in Er3+, Er3+/Yb3+ , Ho3+/Tm3+ singly or doubly doped PLZT ceramics were studied. This thesis details six kinds of upconversion mechanisms and J-O theory. Upconversion, absorption and fluorescence spectra in Er3+, Er3+/Yb3+, Ho3+/Tm3+ singly or doubly doped PLZT ceramics have been measured and characterized. External electrical field induced changes of upconversion spectrum in Er3+/Yb3+ and Ho3+/Tm3+ doubly doped PLZT ceramics have been investigated. A model was proposed based on electrostriction and pyroelctric effect. Theoretically, crystal field theory was applied in calculating the changes of the spectrum intensities based on the changes of symmetry of unit cells around rare earth ions. The calculation values match the experimental results quite well. Some differences have been modified by temperature. Single pass gain of 532, 561, 633, 1550 nm seed light has