地沟油制备生物柴油及相关衍生物合成研究-微生物学专业论文.docx

内蒙 内蒙古科技大学硕士学位论文 PAGE PAGE III Abstract As we all know, the fossil oil is a kind of non-renewable resource energy.Fossil oil was consumed largely along with development of human society. Fossil oil will be depleted in the foreseeable future. The massive consumption of fossil fuel has caused some environmental problems such as air pollution and greenhouse effect.Therefore,many countries have done a lot of research on energy substitution, biodiesel is an important green renewable energy.According to incomplete statistics,China produces about five million tons of waste oil every year.The biodiesel industry adapts to the natinal conditions,and generally used the waste oil as the raw material for biodiesal production.This paper mainly studied on the new types of heterogeneous catalysts for synthetize biodiesel by drainage oil, biodiesel derivative and the by-product glycerol derivatives synthesied.The researches contents are as follows： Used acidification- hydration degumming method to degumming for the drainage oil and drainage oil dehydration. Then drainage oil could be used as raw material for subsequent synthesis of biodiesel by pre-esterification and ester exchange. Comparison with three kinds of magnetic solid acid catalysts which was made in laboratory. Al2O3-ZrO2/Fe3O4 was been determined as catalyst for glycerol esterification of drainage oil.The singal factor experiment results showed that the conditions for preparation:the molor ratio of Al and Zr was 8:1,calcination temperature was 500 ℃,calcination time was 2 hours.The optimal conditions of its catalytic drainage oil esterification which were received by singal factor tests and response surface experiments:the molor ratio of alcohol acid was 0.5,the amount of catalyst was 0.59%,the reaction temperature was 221.4 ℃,the reaction time was 2.55 hours,the esterification rate was 99.67%,the acid value of waste oil could be reduced from 114.82 mgKOH·g-1 to 0.39 mgKOH·g-1 ,attained the demand of homogeneous al