氟碳表面活性剂的性质及其在酸性介质中的缓蚀性能-材料物理与化学专业论文.docx

内蒙 内蒙古科技大学硕士学位论文 IV IV electrochemical method, the inhibition efficiency is more than 90%. But anionic fluorocarbon surfactant C7F15 is not a good corrosion inhibiton for carbon steel in acidic medium. （2）For the mixed systems of fluorocarbon surfactants and ordinary hydrocarbon surfactants CTAB and TX-100, the corrosion inhibition is good, and the inhibition efficiency is more than 80%. The mixed systems with CTAB, the inhibition efficiency reached 96%. For the mixed systems of C8F17, FCI-3 and SDS, inhibition efficiency is more than 70%. It is observed that the amount of fluorocarbon surfactant can reduced by adding ordinary hydrocarbon surfactants. （3）In view of the surface activity for fluorocarbon and hydrocarbon surfactants mixed system, there is a strong interaction between them. Interaction coefficient ?M of fluorocarbon and CTAB mixed system reached -10. ?M of C7F15 and CTAB equals to -40, particularly. Although, C7F15 and SDS are both with negative charge, ?M = -18 for their mixed system. （ 4 ） Main mechanism for the corrosion inhibition mechanization of fluorocarbon surfactants and their mixed system is concluded the adsorption film theory. Key Words：Fluorocarbon surfactant；Mixed system；Surface activity；Corrosion inhibition performance I I 目 录 摘 要II Abstract III HYPERLINK \l _bookmark0 引 言- 1 - HYPERLINK \l _bookmark1 1 绪论- 2 - HYPERLINK \l _bookmark2 1.1 碳氟表面活性剂 - 2 - HYPERLINK \l _bookmark3 1.1.1 碳氟表面活性剂简介 - 2 - HYPERLINK \l _bookmark4 1.1.2 国内碳氟表面活性剂的发展及现状 - 2 - HYPERLINK \l _bookmark5 1.1.3 碳氟表面活性剂的分类 - 3 - HYPERLINK \l _bookmark6 1.1.4 碳氟表面活性剂独特的性能- 4 - HYPERLINK \l _bookmark7 1.1.5 碳氟表面活性剂的用途 - 5 - HYPERLINK \l _bookmark8 1.2 金属的腐蚀与防护- 6 - HYPERLINK \l _bookmark9 1.2.1 腐蚀的定义与分类 - 6 - HYPERLINK \l _bookmark10 1.2.2 影响腐蚀的因素- 8 - HYPERLINK \l _bookmark11 1.2.3 工业中的腐蚀- 9 - HYPERLINK \l _bookmark12 1.3 腐蚀防护技术 - 9 - HYPERLINK \l _bookmark13 1.3.1 缓蚀剂的研究- 11 - HYPERLINK \l _bookmark14 1.3.2 缓蚀的研究方法- 13 - HYPERLINK \l _bookm