导电呋喃吡咯共聚物膜的制备与性能研究-材料学专业论文.docx

摘要 摘要 导电聚合物是 20 世纪 70 年代发展起来的一个崭新的研究领域，其在能源、 光电子器件、传感器、分子导线和分子器件等方面都有诱人的应用前景。与其 他五元杂坏聚合物，如聚 Prt略、聚噬吩相比，聚映喃研究并没有引起人们的关 注。这主要是因为人们无法通过传统的化学聚合法、电化学聚合法获得具有良 好共辄结构、较高导电幕的聚映喃化合物。并且因为映峭本身高的氧化电势， 使其难于通过共聚等方法对其改性。本研究采用新的合成路线，通过糠醒、毗 略间的控甲基化反应实现了共聚，制备得到了具有良好导电性能和机械性能的 映喃·毗咯共聚物膜。我们通过 FT-IR 、UV-Vís 等考察了反应条件、共聚组分的 变化对共聚物性能的影响;通过 FT-IR 、TG 等考察了共聚物的稳定性;通过 4 F下IR 、UV vis 等考察了腆掺杂过程对聚合物结构、辱电率等的影响;通过拉伸 实验等考察了共聚物膜的机械性能。我们并对反应机理、导电机埋进行了分析 和讨论。 实验证明，此合成方法可以有效的实现映喃帽毗咯间的共聚，并且能够避免 聚合过程中映喃的开环，提高生成聚合物的共辄性。制备得到的映峭 J比咯共聚 物膜具有良好的环境稳定性和热稳定性、较高的导电率( 1.011x 10-3 Scm勺和 良好的机械性能(拉伸断裂强度为 10.2 MPa ，杨氏模最为333.6 MPa) 。 关键词 z 导电高分子映喃 J比咯共聚物化学聚合法 Abstract Abstract Since the conductive pol泸n町sw町e discovered in 1970s，they have attracted increasing interest due to their unique properties and wide applications such as energy， optoelectronic devices，sensors，molecular wires and molecular devices，etc. In contrast to other five heterocyc1ic polymers like polypyrrole and polythiophene， poly仙ran is among the most ill-defined conjugated polymers. 刊is is due to its low町 aromaticity and higher oxidation potential compared with other conductive pol严n町s. These inherent defects make polyfuran difficult to be obtained with good conjugated structures by the general chemical polymerization and electrochemical polymerization. Moreover，the problems also induce the failure of optimizations which is carried out by copolymerization. Here，a new synthetic route through the methylolation reaction between furfural and pyrrole was applied.ηle structures and prop即ties of the copolym町S obtained through the method were characterized in detail with in仕ared (IR) and ultraviolet visible (UVvis).ηle infulence of reaction conditions and ωpo切n町 compositions were investigated. ln addition，the mechanism of reaction and conducting were discussed. Finally，several important prop盯ties，including thermal stability and mechanical prop町ties of copolymers were elaborated. ηle data indicated that the ωpoly