负载型铜的氢氧化物催化剂可见光下催化苯乙炔及其衍生物偶联反应的分析-化学;物理化学专业论文.docxVIP

内蒙古师范 内蒙古师范大学硕士学位论文 内蒙古师范 内蒙古师范大学硕士学位论文 万方数据 万方数据 万方数据 万方数据 Cu(II). The initial experiments were carried out using 5.0 wt% Cu(OH)x/Lap as catalyst, phenylacetylene as a model substrate to optimize the reaction condition. The study revealed that polar solvent isopropanol was propitious to the reaction and the Cu(OH)x/Lap could work without base due to its surface alkalescence. The addition of trace base could effectively improve the yield and the opitimal amount of base changed along with the increasement of reaction temperature. The Xe light was used as simulation sunlight in the experiment. It was found that light irradiation had influence on the overall catalytic performance and the light in the wavelengths between 600-800 nm had the maximal influence. And the stronger the light intensity, the larger the contribution was found. These results further confirmed that this homocoupling reaction was driven by visible light. On the other hand, it was observed that the reaction was susceptible to temperature. High yield (99%) was obtained at the reaction temperature to 50 °C. KEY WORDS phenylacetylene, homocoupling, copper catalysts, laponite, visible light 目 录 1 文献综述........................................................................................................................ 1 1.1 研究背景 ................................................................................................................. 1 1.2 端基炔偶联反应及其催化剂................................................................................... 2 Cu(I)助催化作用 2 Cu(I)催化体系 5 Cu(II)催化体系 8 CuNPs 催化体系 10 1.3 铜光催化剂及载体的概述及在反应中的应用...................................................... 11 1.3.1 铜光催化剂概述及在反应中的应用............................................................... 11 1.3.2 铜光催化剂载体的概述及在反应中的应用 ................................................... 14 1.4 论文的设想和目的 ................................................................................................ 15 参考文献 ..................