工业纯镍N6焊接接头组织与腐蚀性能的研究-材料工程专业论文.docx

万方数据 万方数据 III Dissertation Submitted to Hebei University of Technology for The Master Degree of Materials Engineering A STUDY ON MICROSTRUCTURE AND CORROSION PERFORMANCE OF PURE NICKEL N6 WELDED JOINTS by Zhang Lei Supervisor: Prof. Zheng Zhentai May 2015 IV V VI VI 摘 要 工业纯镍 N6 在高浓度碱中有优于其它金属的耐蚀性，因此被广泛用于制碱的蒸 发器中。然而由于其导热性差、熔点高、焊接接头在高温停留时间长等，造成焊接接 头容易成为腐蚀失效的薄弱环节。 本文研究了不同热输入以及是否填充焊丝工艺条件下，工业纯镍 N6 焊接接头的 耐蚀性能，并对比分析了焊接接头和母材的耐蚀性能。试验采用钨极氩弧焊对工业纯 镍 N6 板材进行焊接试验，并在模拟工业制碱的蒸发器出料溶液环境中进行浸泡腐蚀 和电化学测试。然后借助光学显微镜、扫描电镜分析了焊接接头和母材的微观组织并 观察失重腐蚀试样的表面形貌。 本文主要工作以及成果如下：(1)工业纯镍 N6 的 TIG 焊接接头热影响区为粗大 的奥氏体等轴晶，焊缝为粗大柱状枝晶，母材为较细小的奥氏体等轴晶。随着焊接热 输入的增加，焊接接头的晶粒也随之变得粗大。(2)采用实验室浸泡腐蚀试验，通过 失重法计算了不同焊接工艺下获得的焊接接头以及母材的腐蚀深度。发现随着焊接热 输入的增加焊接接头的腐蚀深度也随之增大。(3)对浸泡腐蚀试验的试样表面进行腐 蚀形貌的观察，发现存在点蚀现象。(4)采用电化学测量方法，研究了工业纯镍 N6 的焊接接头和母材在烧碱蒸发器出料溶液中的电化学行为，发现均存在一定的钝化现 象。随着焊接热输入的增加自腐蚀电流密度逐渐增大，在相同的焊接电流下，填丝接 头的自腐蚀电流密度低于不填丝接头。 关键词：工业纯镍 N6 焊接接头 微观组织 腐蚀性能 I II ABSTRACT Pure nickel N6 performs better than other metals in the high concentration of sodium hydroxide corrosion resistant experiment, so that it is widely used in evaporators’ producing process. However, poor heat conductivity, high melting point, exposed to high temperature for too long makes nickel welded joint to be the weak link of corrosion failure. This paper preliminarily explores pure nickel N6 corrosion resistant performance of welded joints under different heat input with filler wire and non-filler wire, and analyzes the corrosion resistance of welded joints and base metal comparatively. Tungsten argon-arc welding(TIG) method is adopted in this experiment. Weightlessness corrosion tests and electrochemical experiments were performed in a simulated industrial caustic soda evaporator discharge solution. OM, SEM, EDS and other test devices are used to obeseve and analyze the microstructures of pure nickel N6 welded joints and the surface morphology of the weight loss corroded specimen. In this paper, main work and achievements were as follows: (1)The microstructure analysis shows