废弃橡胶塑料共热解制取液态油的实验研究-热能工程专业论文.docx

万方数据 万方数据 Abstract The degradation-resistant wastes were very difficult to recyclingly treat, the pyrolysis of waste rubber and plastics powder for liquid fuel production has been investigated in this paper. The pyrolyzed experiments of two blending ratios fuels of rubber and plastics were carried out in TGA, to analysis the pyrolyzed characteristics, kinetic parameters and the influence of the blending ratios, and the verification tests were carried out in a fixed bed system. Then the waste rubber/plastic blends were pyrolyzed in a fixed bed system with few corn stalk additive to produce pyrolyzed oil, and the co-pyrolysis characteristics were analyzed. The influence of Fe2O3 and CaO as catalysts on the pyrolysis of waste rubber and plastics was to investigate in the next. In the end, the pyrolysis experiments were carried out in a continuous feeding rotary kiln pyrolyzer system, and the influence of residence time and temperature on the pyrolysis of waste rubber and plastics has been investigated. According to the TGA experiments, the pyrolysis process of rubber/plastics blends occurred to two stages, the first and the main stage achieved 85% of the whole pyrolysis, while the blending ratios did less influence on the pyrolysis temperature, but clear influence on the pyrolysis rate. The suitable blending pyrolysis temperature was 500℃. From the pyrolyzed oil collection in the fixed bed facility, the oil was of 38% yield, and HHV of 35MJ/kg. In the experiments of co-pyrolysis in a fixed bed system, the oil yield and liquid calorific value were increased by co-pyrolysis of rubber/plastics compared with the pyrolysis of the each material. When the mass proportion of rubber was 60%, the pyrolyzed oil yield rate reached the highest point. Adding 10% stalks into blends fuel contributed to the higher pyrolyzed oil production. When the ratio of rubber and plastics was 4:1 with 10% stalk additive, the oil yield achieved highest and the oil yield increased by 10.