酚醛树脂胶粘剂的合成及改性分析-有机化学专业论文.docxVIP

固体含量 1.6%的有机硅 8427 和 3g 即占总固体含量 0.96%的蔗糖复合 作为改性剂，可得到拉剪强度高达 7.23MPa 的酚醛树脂胶粘剂，其胶 膜能对折 9 次，柔韧性较好；采用 5g 即占总固体含量 1.6%的有机硅 8427 和 2g 即占总固体含量 0.64%环氧 E51 复合作为改性剂，可得到 拉剪强度高达 7.17MPa 的酚醛树脂胶粘剂，其胶膜能对折 11 次，柔 韧性很好；采用 5g 即占总固体含量 1.6%的环氧 E51 和 2g 即占总固 体含量 0.64%的蔗糖复合作为改性剂，可得到拉剪强度高达 8.13MPa 的酚醛树脂胶粘剂，其胶膜能对折 8 次，柔韧性较好；采用 5g 即占 总固体含量 1.6%的环氧 E51 和 1.5g 即占总固体含量 0.51%的 PEG 复 合作为改性剂，可得到拉剪强度高达 8.50MPa 的酚醛树脂胶粘剂，其 胶膜能对折 10 次，柔韧性较好；采用 3g 即占总固体含量 1.2%的聚 醚 N210 或者 PEG 和 1.5g 即占总固体含量 0.6%的蔗糖复合作为改性 剂，可得到拉剪强度分别高达 7.50MPa 和 7.83MPa 的酚醛树脂胶粘 剂，其胶膜分别能对折 9 次和 10 次，柔韧性很好。 （4）将合成的各类型酚醛树脂胶粘剂分别用于软木屑、粉碎状 秸秆、长条状秸秆、谷壳等粘接，并将其压制成块；同时用其粘接物 联网电子标贴。测试性能得出：PEG 和环氧 E51 复合改性酚醛树脂 胶粘剂粘接软木屑等得到的块状木材的强度和柔韧性都很好；电子标 贴粘接后的强度和柔韧性也达到要求。 关键词: 酚醛树脂胶粘剂；增韧改性；耐热改性；合成工艺 ABSTRACT Phenol-formaldehyde resin was synthesized by two step alkaline catalytic one step reflow, Epoxy, organic silicon, polyethylene glycol and sugar were adopted to modified phenol-formaldehyde resin to increase the flexibility of adhesive film with high tensileshearstrength and lower the free formaldehyde content. Organic silicon was used with sugar or epoxy, epoxy was used with sugar or polyethylene glycol (PEG), polyethylene glycol was used with sugar to modified phenol- formaldehyde resin to increase the flexibility and tensileshearstrength. Performance and structural characterization of product was tested by mechanical properties tester, Fourier transform infrared spectrum analyzer (FTIR), thermogravimetric analyzer (TGA), spectrophotometer, viscosity testing and other means of testing, in order to establish the optimal reaction conditions .The main findings are as follows, (1)The result shown that the best phenol-formaldehyde resin with higher then 5.01MPa on tensileshearstrength and lower then 0.077% on free formaldehyde content was prepared from phenol and formaldehyde of molar ratio 1:2 in aqueous solution which was reacted 40 minutes at 70℃, 20 minutes 80℃and one-step reflow 50minutes, and solid content was 50%, the amount of catalyst was 25% of the ph