铁含量对永磁性材料锶铁氧体磁性能的影响.doc

摘 要 锶铁氧体由于其较强的各向异性和适中的磁化强度使其成为重要的磁性材料，广泛 应用于高密度磁记录、高性能永磁体、微波材料、微波吸收材料等领域。因此，锶铁氧 体作为一种重要的永磁材料将会宥非常广阔的应用前景。 本研究主要采用共沉淀法合成锶铁氧体样品。以FcC12、SrCl2、NaOH、聚乙二醇 等做为原料制作，再将液体样品进行抽滤、干燥，再经过马弗炉煅烧得到样品。最盾着 重研究铁锶比、碱比和煅烧温度等因素对粒子的微观结构与性能的影响。 利用高压透射电子显微镜（TEM）、振动磁强计（VSM） X射线衍射仪（XRD）和 扫描电子显微镜（SEM）等先进仪器对样品粒子的粒径，分散性，磁性及晶相进行表征 并讨论，最￡；得出最佳的铁锶比和其他实验条件组合。 关键字：锶铁氧体；共沉淀法合成；铁锶比；磁性 The Strontium Hexaferrite Synthesized by Co-precipitation Method Abstract Hexagonal ferrites SrFeuOw are widely utilised as permanent magnets for microwave devices，high-density magnetic recording and bubble domain memories. This is due to their relatively strong anisotropy and moderated magnetization. Therefore, Sr-ferrite，as a permanent magnet material will be important to have a very broad prospects. The co-precipitation method was applied for the preparation of SrFeuOw in this paper. Chemically grade FeCh，SrCh，NaOH，Poly vinyl alcohol were used as starting materials. Then liquid the samples，dry，and then after muffle furnace Calciner get samples. Finally focusing on Fe3l/Sr2t mole ratio, NaOH dosages，calcined temperatures and other factors on the micro-particle structure and properties of the impact. Then the structure,magnetic and other behavior of nanosized particle were studied by using advanced instruments of TEM，XRD，VSM and SEM，the better Sr-ferrite particle can be obtained. Keywords: Sr-ferrite; Co-precipitation synthesis; Fe3+/Sr2 mole ratio; magnetic TOC \o 1-5 \h \z 摘. S I HYPERLINK \l bookmark2 \o Current Document \h Abstract II 弓 IW 1 HYPERLINK \l bookmark5 \o Current Document \h 1 纳米材料 1 1. 1 纳米材料概念 1 1.1.2纳米材料的发展 2 1.1.3纳米材料的特性 2 HYPERLINK \l bookmark6 \o Current Document \h 1.2铁氧体纳米粉体材料 3 1.2.1铁氧体概述 3 1.2.2铁氧体磁性材料的分类及应用 4 HYPERLINK \l bookmark7 \o Current Document \h 1.3铁氧体的制备方法 5 1.3.1化学共沉淀法 5 1.3.2水热法 6 1.3.3微乳液法 6 1.3.4超临界法 7 1.3.5自蔓延高温合成(SHS)法 7 1.3.6溶胶-凝胶法 7 1.3.7分散剂聚乙烯醇(PVA) 8 HYPERLINK \l bookmark8 \o Current Document \h 1.4研究内容和意义 9 1.4.1课题研究的口的和意义 9 1.4.2课题研究任务 9 HYPERLINK \l bookmark9 \o C