串联质谱法测定豆芽中氯苯氧乙酸钠-食品安全质量检测学报.PDF

6 10 Vol. 6 No. 10 2015 10 Journal of Food Safety and Quality Oct. , 2015 - 4- * 卢高超 , 王小娟, 李红光, 穆登峰, 刘永健 (, 712000) 摘 要: 目的 4--方法 0.01 mol/L , , , 0.1%(FA), Hypersil GOLD aQ (100 mm2.1 mm, 3 μm) , (SRM)结果 0.005 mg/kg, 1~100 ng/mL , 0.999879.1%~104.7%, 5%(n=6) 结论 , , , 4- 关键词: -; ; ; 4- Determination of sodium parachlorophenoxy in bean sprouts by high performance liquid chromatography-tandem mass spectrometry * LU Gao-Chao , WANG Xiao-Juan, LI Hong-Guang, MU Deng-Feng, LIU Yong-Jian (Shaanxi Keyi Sunshine Test Technology Services Co., Ltd ., Xianyang 712000, China) ABSTRACT: Objective To establish a method for determination of sodium parachlorophenoxy (4-CPANa) in bean sprouts by high performance liquid chromatography tandem mass spectrometry (HPLC-MS/MS). Methods The soybean sample was extracted with 0.01 mol/L sodium hydroxide solution, and the extracting solution was recovered by diethyl ether in acidic condition. After centrifugation, the organic phase was concentrated completely and re-dissolved with methanol. The sample was separated by a Hypersil GOLD aQ column (100 mm2.1 mm,