铝合金环保型无烟化学抛光工艺的研究.docVIP

铝合金环保型无烟化学抛光工艺的研究 ? 2O?Sep.2009Eiectroplatingamp;PollutionControlV0I.29NO. 5 [8] [9] ZheludkevichML,SerraR,MontemorM.F.et口Z. Nanostructuredsolgelcoatingsdopedwithceriumnitrateas pre-treatmentsforAA2024一T3:Corrosionprotection performanceEJ].ElectrochimicaActa,2005,51(2):208— 217. TrabelsiW,DhouibiL,TrikiE.eta1.Anelectrochemical andanalyticalassessmentontheearlycorrosionbehaviourof [1o] galvanisedsteelpretreatedwithaminosilanes[J].Surfaceamp; CoatingsTechnology,2005,192(2):284—290. FerreiraMGS,DuarteRG,MontemorMF,eta1.Silanes andrareearthsaltsaschromatereplacersforpre-treatments ongalvanisedsteel[J].ElectrochimicaActa,2004,49(17): 2927—2935. 收稿日期:2009—04—13 ? 抛光? 铝合金环保型无烟化学抛光工艺的研究 AResearchonEnvironmentFriendlySmokelessChemicalPolishing TechnologyforAluminumAlloy 孙洪波.李轶,熊仕显,袁孚胜 (江西理工大学材料与化学工程学院,江西赣州34100O) SUNHong-bo,LIYi,XIONGShi-xian,YUANFu-sheng (FacultyofMaterialandChemicalEngineering,JiangxiUniversityof ScienceandTechnology,Ganzhou341000,China) 摘要:为了消除传统的三酸抛光对环境和人体健康的危害,开发了以磷酸一硫酸为基础液,并加入添加剂的无烟化学抛光工 艺.首先研究了不合添加剂时各种因素对抛光质量的影响,并在此基础上选出最佳工艺参数,确定复合添加剂的质量浓度. 结果表明:在H3PO4(体积分数为85%):H2SO4(体积分数为98)一2:1,A1”8～10g/L,WYZ-1型复合添加剂10g/L, 95～11O℃,1～2min工艺条件下,可以提高抛光质量,抑制点蚀,获得较好的抛光效果,成功地解决了化学抛光中的黄烟污染 问题,满足工业生产的需要. 关键词:铝合金;化学抛光;抛光剂;添加剂 Abstract:Inordertoeliminatetheharmtohumanhealthcausedbytraditionalthree-acidspolishingmethod,asmokeless chemicalpolishingprocesswasdeveloped,whichtakesphosphoricacid—sulfuricacidasitsbasefluid,andalsoinvolves additive.First,theeffectsofvariousfactorsonpolishingqualitywereinvestigatedwhentheadditivewasnotinvolved,thenon thisbasisthebesttechnologicalparameterswereselected,andthemassconcentrationofthecompoundadditivewasalso determined.Theresultsindicatethatundersuchtechnologicalconditionsas:H3PO4(volumefraction85):H2SO4(volume fraction98)2:1;AI8～10g/L,WYZ-1compoundchemicaladditive10g/L;95～110.C;1～2min,thepolishing qualitycanbeimprovedandpittingcorrosionsuppressed,resultinginagoodpolishingeffect,thushavingsolvedtheyellow- smokeprobleminchemicalpolishing,wh