表面引发聚合反应研究进展3.PDF

第 17 卷 第 6 期 化　学　进　展 Vol. 17 No. 6 2005 年 11 月 PROGRESS IN CHEMISTRY 　Nov. , 2005 表面引发聚合反应研究进展 倪　刚　杨　武 　何晓燕　薄丽丽　吕维莲 (西北师范大学化学化工学院 甘肃省高分子材料重点实验室 兰州 　730070) 摘 　要 　表面引发聚合反应作为一种新的聚合反应可广泛应用于固体基底的表面修饰与改性。结合分 子自组装技术 ,几乎各种类型的聚合反应都有可能在固体基底表面进行。本文对表面引发聚合反应的研究 进展进行了综述 ,对反应类型、实验方法、研究动向以及在合成聚合物刷、形成图案化聚合物薄膜等方面的应 用与发展前景作了介绍与讨论。 关键词 　表面引发聚合反应 　自组装单分子层 　图案化聚合物薄膜 　聚合物刷 ( ) 中图分类号: O631. 5 　文献标识码 : A 　文章编号 : 1005281X 2005 Advances in Surface Initiated Polymerization Ni Gang 　Yang Wu 　He Xiaoyan 　Bo Lili 　L üWeilian (College of Chemistry and Chemical Engineering , Northwest Normal University , Gansu Key Laboratory of Polymer Materials , Lanzhou 730070 , China) Abstract 　The recent developments of surface initiated polymerization are reviewed. Surface modification of the polymers is an important area both for application and basic research. As a new kind of controlled polymerization techniques , surface initiated polymerization can be used to modify the surfaces of the solid materials and tailor substrate properties. It opens a new way for the modification of solid substrates for their potential applications in a variety of technological fields. The theoretical and the experimental approaches and the research prospects of the surface initiated polymerization are extensively introduced in this paper. The applications of this technique including the patterned nanostructures of polymer films and polymer brushes are also discussed in detail. Key words 　surface initiated polymerization ; selfa