高分散性白炭黑-丁苯橡胶复合材料的研究-化学工程专业论文.docxVIP

高分散性白炭黑一丁苯橡胶复合材料的研究Abstract 高分散性白炭黑一丁苯橡胶复合材料的研究 Abstract The silica surface modification call not only improve their dispersion among the rubber, and may form filler-matrix network structure，thus the rubber matrix has some reinforcing effect，extend the life of rubber products．With the subject cationic surfactants 1 83 1 of silica surface modification，prepared the copolymer of silica and polystyrene-butadiene、析血lli曲 dispersion by in—situ，solve the uneven dispersion and interface compatibility issues，It Can provide new ideas and methods for the study of silica-SBR composites preparation，and investigated materials processing properties，mechanical properties，dynamic properties and wear resistance，the specific contents are as follows： l、111e silica is modified by the cationic surfactant 1 83 1 and prepared silica—SBR composites by in situ emulsion polymerized，in this way it can solves dispersion mention for silica．Adding to the reaction system AO 1 805 Can improve the polymerization reaction rate． 2、To 1H NMR and¨C NMR tests found that：gum prepared in-situ silica-styrene butadiene rubber,butadiene content of cis-1，4 and trans-1，4 structure and a vinyl content did not change，in which the bound styrene content of between 21．5％to 23．5％，butadiene cis一1，4 structure content between 1 0％to 1 2％，trans-1，4 structure content between 73％to 75％，the vinyl content of about 1 5％． 3、To TEM，it can be found that，compared with the traditional mechanical mixing method，Mixture of silica and polystyrene-butadiene in emulsion polymerization with in—situ method，in which the silica dispersion and interface compatibility has been greatly improved． 4、The processing performance and mechanical performance test indicate that the Mooney，eIongation at break and resilience of silica-styrene butadiene rubber composites preparated by the in—situ preparation are higher than the composites preparated by traditional mechanical blending preparation，however,shaw hardness and permanent deformation rate is low