高取代度淀粉醋酸酯与淀粉接枝PMA作为生物降解材料的改性分析-材料学专业论文.docxVIP

摘要本辑巍瓣嚣瓣簿程罨残～耱爱囊秘簿瓣爨料謇砉瓣，代癸臻蘸奁一次羧缺 摘要 本辑巍瓣嚣瓣簿程罨残～耱爱囊秘簿瓣爨料謇砉瓣，代癸臻蘸奁一次羧缺 镶蠡、毯装糖辩莓镄蠛大爨筏耀戆避鼹爨料粼鼹，斌藤藏辍邋爆爨料壤雾物 潦袋靛环蕊污染鲻藤。漾越嚣蕊疆巍了淀耪程激戆簿辩耱辩壤皱懿舞黪德攀 改彀产秘，麓取代壤淀粉醋酸黼颡淀粉搂技PMA。 潺遵实验礴究，确爨了辩警繁磺黢(TPS)魏潮罄舞崴代魔淀狳醋酸酪鹣 含矮脊靛熬磷德麓。懑辩耨擦骢“予法”裂备魇成方式，大黼魔盼鼯羝了垒 产娥本，隽鬻墩捉发淀耪靛黢黪粒工簸纯生产键逶了条髂。安骏旗窥了“予 法”割餐熬袋徒茨寂祭髂，舞对胡褥煞菇凝找瀵淀粉骥簸熬滋黪了瀛燮魏缝 测试，凝瀵薅蒋滚麓滠痰篱，融凌大，蘸熔融按凑黪爨臆襁，趣王袋毽存蹙 鼹搂； 安骏茨麓酸稚较(CAN)炎每l发裁，谗谂了凌技菸聚簿箴，零，淀耪麓鬣 魄、警l发麓浓澄襄犊较肇赫翅黛鼯接壤爨蘩爱墩及箕产黪拣壤媳黟蛹，确宠 了掰餐淀黪羧技PMA静会避爱藏条铃。邋避熔融捺寝蜜验，笈凌雠褥蕊淀糙 接技PMA鬃离一囊豹热鬻健魏锻壤，毽蠢予糠承稼鲶鬻誉够，翱王遵耧审餐 弱发黧焦纯。 渫熬述瓣麓裴我瀵淀耪戆羧爨窝浚耱羧攘PMA避簿了=羧潋姓鲍尝试。 装溅殴蠖黻鬻赣耪豢毪铰麓，莛滋磐馥壤举壤憋。辩淀辫续棱pMA避行不黻 佬辑菠褴，褥瓤靛接棱～鑫躐纯淀狳程熬秀攀橼震鞘艇王瞧穗主帮程一宠穗 黢懿褪辫。戴豁，瓣较技～己酸纯淀粉还进行了骧黢锻续究敬蕊静麟究，羧 麓娄凝羧钙添瓣髫必碡嵇％发毒辩，剪骥获褥簇辩较鲑戆鬻赫疆躞翔麟襞{枣长 率，黼辩降酝了戏零。 燕鹊游$囊秘辩麟；淀粉；淀粉精黢繇；彀代壤；不瓣爨；淀粉装彼PMA； 接棱一己鼗纯 ABSTRACTThe ABSTRACT The study aims at finding a completely biodegradable material as a substitute for general plastics largely used in snack packet and packing，in order to alleviate the pollution caused by castoffs of this general plastics．The paper placed emphases on discussing starch acetate of high degree of substitution and starch graft PMA，as chemical modification derivates of starch in the field of biodegradable materials． The paper chose P-toluenesulfonic acid(TPS)as the optimum catalyst of preparing starch acetate of high degree of substitution，and put forward a novel technics of“dry method”that resulted in a rather decrease in cost and a advantage for industrialized production of it．The optimum reaction conditions of“dry method”was determined，and through rheology analysis on the prepared starch acetate of high degree of substitution，it found that the fluid temperature and the viscosity of the melt were rather high，and there were some difficulties in shaping due to the melt exhibited brittle． The paper discussed the effects on the reaction and the properties of output by the method of graft copolymerization，the proportion of water to starch，the concentration of initiator and the dosage of monomer taking ammonium eerie nitrate(CAN)as the catalyst，and determined t