水溶性CdHgTe合金量子点制备和表征.PDFVIP

第26 卷 第7 期 无 机 材 料 学 报 Vol. 26 No. 7 2011 年7 月 Journal of Inorganic Materials Jul., 2011 文章编号: 1000-324X(2011)07-0735-04 DOI: 10.3724/SP.J.1077.2011.00735 水溶性 CdHgTe 合金量子点的制备与表征 王益林, 童张法, 陆建平, 黎建辉, 周立亚 (广西大学 化学化工学院, 南宁 530004) 摘 要: 以巯基乙酸为稳定剂, 在水溶液中加热CdCl2 、HgCl2 和 NaHTe 的混合物直接合成CdHgTe 合金量子点. 分 别用荧光光谱、红外光谱、X 射线衍射及透射电镜对其光谱性能、表面基团和结构形貌进行了表征. 结果表明, 合 金量子点的发射波长在 536 到 688 nm 范围内连续可调, 掺杂后量子点的发射光谱变宽, 半高峰宽为 70~90 nm; CdHgTe 的荧光量子产率介于 1.5%到 6.7%之间; 巯基与 CdHgTe 量子点表面的 Cd2+离子发生键合, 而使巯基乙酸 结合于量子点表面; 合金量子点具有闪锌矿结构; 量子点分散性好, 形貌呈颗粒状. 关 键 词: 量子点; 荧光; 制备; 表征 中图分类号: O657 文献标识码: A Synthesis and Characterization of Water-soluble CdHgTe Alloyed Quantum Dots WANG Yi-Lin, TONG Zhang-Fa, LU Jian-Ping, LI Jian-Hui, ZHOU Li-Ya (School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China) Abstract: CdHgTe alloyed quantum dots (QDs) were directly synthesized in aqueous solution by heating a mixture of CdCl , HgCl and NaHTe in the presence of thioglycolic acid as stabilizer. The obtained QDs were characterized 2 2 by fluorescent spectroscope, fourier transform infrared spectroscope (FTIR), X-ray powder diffraction (XRD) and transmission electron microscope (TEM), respectively. The results show that the technique lead to the formation of CdHgTe alloyed QDs with broad fluorescence full-width at half-maximum (70−90 nm), moderate photoluminescence quantum yield (1.5%−6.7%), and a broad emis