Ag与Ce掺杂改性TiO2光降解催化剂的制备光催化性能的研究-化学工程与技术专业毕业论文.docxVIP

透射电子显微镜(TEM)对产物进行了表征。以亚甲基蓝(MB)为降解物， 考察了不同Ag含量和不同煅烧温度对样品的光催化性能影响。结果表明， 掺杂Ag后，增大了样品的比表面积，800℃时，Ag的引入抑制了Ti02锐 钛矿向金红石相的转变，掺杂后Ti02的光催化活性大大提高，在500℃煅 烧温度下，当ag的摩尔分数为1％时，在紫外光照射下，经过180 min光 催化实验，对MB的降解率达到90％。 (4)采用溶胶．凝胶法制备了Ce和Ag掺杂的Ce—Ag—Ti02光降解催化 剂。以亚甲基蓝为光催化反应的模型污染物，探讨不同掺杂元素的含量、不 同煅烧温度与其降解率的关系。通过X射线衍射(XRD)、场发射扫描电 子显微镜(FE．SEM)、N2吸附．脱附(BET)、透射电子显微镜(TEM)对 产物进行了表征。结果表明，共掺杂Ti02的比表面积达到123．3 m2-g～，远 远大于未掺杂和单掺杂的样品。此外，Ce和Ag的引入抑制了Ti02锐钛矿 向金红石相的转变，在500℃煅烧温度下，经紫外光照射180 min，共掺杂 Ti02对MB的降解率达到92％，明显高于未掺杂和单一掺杂的样品，且ce 和Ag的最佳摩尔掺杂量为1．5％和O．5％。 关键词：二氧化钛，纳米粒子，Ce掺杂，Ag掺杂，光催化性能 II 万方数据  PREPAR』▲TIoN AND PRoPERTIES OF Ag AND Ce IoNS DOPED Ti02 PHOTOCATAI』yST ABSTRACT Titanium oxide(Ti02)，as one of obbligato transition semiconducting material，has been attracted much more attention by researchers due to its novel strllc眦s and superior properties．Ti02 has been widely used in many fields including catalytic chemistry,biological chemistry,medical science，et al， because of cheap，easy acceptance，non-toxicity,excellent photo-stability． However,the large bandgap(anatase-3．2eV)led some weaknesses such as hi曲-energy radial excitation and rapid combination of photoreduced charge and limited its further applications．Many efforts have been attempted to enhance the charge separation efficiency and the absorption under the irradiation of UV light by tuning of the band gap of Ti02 by Ag and rare earth elements doped Zi02 to increase photocatalytic activity．So our work is to prepare of Ti02 doped by rare earth element and Ag to improve their photocatalytic performance．Our work is summarized as follows： (1)In this paper,Ti02 nanoparticle doped with varying content of Ce was prepared by a sol-gel method using Ti(OC4H9)4 and C2HsOH．The samples were characterized by X—ray diffraction(XRD)，scanning electron microscopy(SEM)， N2 adsorption-desorption isotherm(BET)，X-ray photoelectron spectroscopy (xPs)，and transmission electron microscopy(TEM)．The photocatalytic activity of Ce．doped Ti02 microspheres was evaluated by