高级氧化技术在修复多环芳烃污染土壤中的研究-化学工程专业论文.docxVIP

万方数据 万方数据 河北科技大学硕士学位论文 11 AbstractAdvanced Abstract Advanced oxidation technology with its high efficiency，complete degradation Ot p011utants is widely used in the degradation of soil contaminants．Chlorine dioxide(C102) catalvtic oxidation of is a kind of advanced oxidation technology．The degradations of antkacene—contaminated soil using chlorine dioxide as oxidant and three kinds of catalysts prepared by different processes were studied in the thesis．The following innovative progresses were achieved in this work： 1、CuO．montmorillonite Was prepared using Na2C03 precipitation method and its s仃uctLlre was deteHnined by XRD， IR，TEM and EDS． C102 catalytic oxidation degradation of anthracene．contaminated soil was studied in detail using CuO．montmorillonite as a catalyst． 2、Fe304．CuO@montmorillonite was prepared by coprecipitation method and used as catalyst for the degradation of anthracene in soil by C102 oxidation process to reuse the catalyst conveniently by magnetic separation and avoid the secondary pollution to elwironment．Its stmcture waS determined by XRD，IR，TEM and EDS．C102 catalytic oxidation degradation of anthracene．contaminated soil was studied in using Fe304。CuO@ montmorillonite．The degradation effect of the catalyst Was stable after 8 times recycle· 31 Fe304@CuO composite material with core—shell structure Was prepared using hvdrothermal method and its structure was determined by XRD，IR，TEM and EDS．The results showed that CuO Was coated on the surface of hollow Fe304 microspheres· A ntbracene degradation rate decreased less after eight recycles，indicating good repeatability of Fe304@CuO． The chlorine dioxide(C102)oxidative degradation of anthracene—contaminated soil was studied in detail using three kinds of catalysts．The operating parameters such as the C102 concen心ation，catalyst dosage，reaction time and pH were evaluated．1)The optimal condition with CuO montmorillonite as catalyst Was as follows：anthracene concentration 89．9mg／kg，C102 concentrat