ⅡⅥ族纳米晶的生长动力学与超快光光谱的分析.docxVIP

摘要摘 摘要 摘 要 II．Ⅵ族半导体纳米晶材料由于其优越的结构与光学特性，有着巨大的应用 潜力，引起学界的广泛关注。而利用飞秒脉冲激光观测微观世界的超快过程， 也得到了人们越来越多的重视。本文以Ⅱ．VI族纳米晶为研究对象，研究其生 长的动力学过程及光谱特性。本文目的在于深入了解纳米晶的形成过程，分析 其基本的物理机制，通过测试超快光谱研究纳米晶中的超快过程，建立纳米晶 体中能量传递的模型，为实际应用提供实验与理论依据。论文的主要内容如下： 1．采用热注入方法，尝试制备了CdS纳米晶、CdS／ZnS核壳结构纳米晶及 CdS／ZnSe／ZnS核壳壳结构纳米晶。通过改变包覆剂油酸的浓度和反应物的浓 度，考察了它们对反应产物质量的影响，对纳米晶的成核机理和生长机理进行 了分析。 2．根据紫外可见荧光光谱测试，分析CdS纳米晶和CdS／ZnS核壳结构纳米 晶的基本能级结构和发光过程。 3．应用飞秒激光技术研究了纳米晶的超快动力学过程。采用上转换方法测 试了CdS纳米晶和CdS／ZnS纳米晶的超快荧光光谱，测量不同时间范围内激子 的弛豫曲线，探讨了的纳米晶中能量传递的过程。 关键词：II．VI族纳米晶生长动力学超快荧光光谱 AbstractII—VI Abstract II—VI semiconductor nanocrystal material is of increasing int凹est since tlleir out·standing structural and optical properties．This thesis presents investigation on growth kinetics and spectral characteristics of II·VI semiconductor nanocrystal as research object The intention of this research is to thoroughly study the growth processes of nanocrystal and analyze the physical mechanism，theorize the model of energy transferring in nanocrystal by measuring ultrafast spectra of nanocrystal，and to provide the experimental and theoretical basis for application．The main contents of the thesis is as following： 1．Synthesized CdS nanocrystal，CdS／ZnS core／shell nanocrystal and CdS／ZnSe／ZnS core／shell／shell nanocrystal by using hot-injection approaches．We change the concentration of covering oleic acid and reagent cadmium oxide to observe how they affect the quality of products．Analyzed the mechanism of nucleation and growth of nanocrystal． 2．We meIasure UV-vis spectra of CdS nanocrystal and CdS／ZnS core／shdl nanocrystal，and analyze their basic band structure and luminescence process． 3．Using femtosecond laser technology,the ultrafast dynamics processes of exciton in nanocrystal are studied．up-conversion fluorescence measured of fcrntosecond time-resolved spectroscopy applied in CdS nanocrystal and CdS／ZnS nanocrystal．The transient decaying curves of exciton are characterized in different time range，and processes of energy transferring ale discussed．