热处理方式对苯甲基化木材制备的聚氨酯树脂微相-林产化学与工业.PDF

25 1 Vo.l 25No. 1 2005 3 Chem istry and Industry of ForestProducts M ar. 2005 * * 李厚萍, 程 发 , 魏玉萍, 潘 虹 ( 天津大学理学院化学系, 天津 300072) : 以二价酸酯[ dibasic esters, DBE(己二酸戊二酸 丁二酸的混合酯) ]与乙酸 丁酯混 合溶 液化的苯甲基化木材溶液与三羟甲基丙烷甲苯二异氰酸酯预聚物为固化 进行反应制 备聚氨酯树脂对树脂进行不同的热处理, 利用 FT- IRDSCDTA 及TG 等测试手段, 研究了 LI P 热处理方式对树脂的结构和热性能的影响结果表明,不同热处理方式下的微相分离程度为: 常温固化退火处理 淬火处理;硬段初始分解温度为: 常温固化退火处理 淬火处理; 软段的初始分解温 度为: 常温固化退火处理 淬火处理 : 聚氨酯; 微相分离; 苯甲基化木材 : TQ334. 1 : A : 0253- 2417( 2005) 01- 0105- 04 EFFECT OF EAT TREATMENT ON M ICROSP ASE SEPARATION OF BENZYLATED-WOOD-BASED POLYURET ANE LI ou-ping, C ENG Fa, WEIYu-ping, PAN ong (D ep ar tm ent of Chem istry, Schoo l of Sc ience, T ianj in Un iv ersity, T ianj in 300072, Ch ina) Abstract: Polyurethane resinwas synthesized by benzylatedwood solution using m ixture of dibasic esters(DBE) and n-butyl acetate as solventsw ith the adduct of toluene diisocyanate( TDI) and trihydroxymethyl propane, and then the resinwas treated by different heating methods. FT-IR, DSC, DTA andTG areused to characterize the resin. A ll results showed that heat treatmentmethod plays an mi portant role on m icrosphase separation and thermal property of the resin. The degrees of microphase separation under different heat treatment methods are in the sequence of: normal temperature solidifying( S) annealing(A) quenching(Q). The initialdecomposing temperatures during hard-stage are in the sequence of: S A Q, while the initial decomposing temperatures during soft-stage are in the sequen