eu3荧光共聚物及聚合基复合材料的制备与性能研究.docxVIP

优秀毕业论文 精品参考文献资料 许传杰 Eu3+ 许传杰 Eu3+荧光共聚物及聚合物基复合材料的制备与性能研究 三 Abstract Rare earth polymers luminescence material have become excellent luminescence materials，this is due to lanthanide ions，speculiar characteristics． Advantages such as high strength，color pure fluorescence because unique structure and nature of rare earth ions，and low exciting energy,high fluorescence efficiency, soluble in organic solvents the same as organic compounds can be found in rare earth luminescent organic materials．So a new way Was provided to people to explore new light energy and new light-emitting materials． In this paper,the research was focus on synthesis of new rare—earth luminescent polymer,got down to work by synthesis of rare earth complexes、析tll polymerization activity,studied synthesis the luminescent copolymers and their copolymerization and the impact factors of their luminance，and discussed the CO—luminance between rare earth ions in polymer matrix．Reaching work was started from the following aspects： 1．Synthesis the luminescent complexes with polymerization activity and studying their properties Eu(MA．A)3pheli luminescent complexes were prepared by co-precipitation method in this paper．Europium oxide was used as raw material，Q—methyl acrylic acid as the first ligand and 1，1 0-phenanthroline(phen)as the second ligand．The complexes Can be used in the synthesis of bonding type rare earth polymer．The composition，structure and properties of the complexes were characterized in this paper．Element analysis showed that the composition of complex is Eu(MAA)3phen． XRD analysis showed the good crystalline properties of the complexs．The single crystal analytical shows the ligands bi-coordinated with the RE ions in the complexes．UV absorption spectra showed the characteristic absorption peak of phen．The result shows the mainly energy absorption peak Was the兀一兀}transition peak of phen in ultraviolet region．STA analysis shows the good thermal stability of the the complexes．The thermal stabi