以纳米二氧化钛为载体Ag(I)表面印迹聚合物制备和应用.PDFVIP

第9 卷第7 期 Vol.9 No.7 2016 年4 月 April 2016 以纳米二氧化钛为载体的Ag(I)表面印迹 聚合物的制备及应用 刘彦雄，刘笑岚，谭文祥，刘 鹏，曹秋娥* （云南大学化学科学与工程学院，昆明 650091 ） 摘要：基于软硬酸碱理论，选择了主要以N 为配位原子的烯丙基脲（NAU ）为功能单体，在系统优化了功能 单体、纳米二氧化钛和交联剂用量的基础上，采用0.1 mmol Ag(I)为模板，50 mg 纳米二氧化钛为载体，0.3 mmol 烯丙基脲为功能单体，3 mmol 乙二醇二甲基丙烯酸酯（EGDMA ）为交联剂，以表面印迹技术制备了一种Ag(I) 离子印迹聚合物（ion-imprinted polymer ，IIP ）。该印迹聚合物在10 mL 含有50 mg/L 的Ag(I)水溶液中对Ag(I) 的平衡吸附量为34.16 mg/g ，印迹因子为1.94，用其制备的固相萃取小柱在优化的萃取条件下，对Ag(I) 的萃 取率达到了78% ，而对Ir(IV) 、Pd(II) 、Ru(III) 、Rh(III) 、Au(III)和Cu(II) 的萃取率均在15%以下。 关键词：分析化学；Ag(I) ；离子印迹聚合物；表面印迹技术；纳米二氧化钛；固相萃取 中图分类号：O631 文献标识码：A 文章编号：1674-2850(2016)07-0739-07 Preparation of Ag(I) surface imprinted polymer with nano-titanium dioxide as supporter and its applications LIU Yanxiong, LIU Xiaolan, TAN Wenxiang, LIU Peng, CAO Qiue (School of Chemical Science and Technology, Yunnan University, Kunming 650091, China) Abstract: Based on the soft and hard acid and alkali theory, N-allylthiourea (NAU), which can use N as coordination atom, was selected as functional monomer for the preparation of Ag(I) ion-imprinted polymer (IIP). After the amounts of functional monomer, cross-linking agent and nano-titanium dioxide were optimized, a Ag(I) ion-imprinted polymer was obtained by surface imprinting technique with 0.1 mmol Ag(I) as template, 0.3 mmol NAU as functional monomer, 50 mg nano-titanium dioxide as supporter, and 3 mmol ethylene glycol dimethacrylate (EGDMA) as crosslinker. The adsorption capacity and imprinting factor of this IIP in 10 mL of aqueous solutions containing 50 mg/L Ag