油溶性降粘剂的合成及评价-毕业设计论文(学术).docVIP

本科生毕业设计（论文） 题 目： 油溶性降粘剂的合成及评价 学生姓名： 系 别： 化学化工系 专业年级： 应用化学2008级 指导教师： 2012年6月20日 中国石油大学胜利学院本科毕业设计（论文） 摘　　要 稠油粘度高，密度大，流动性比常规资源差，所以对稠油降粘剂的研究及其作用机理的探讨具有重要意义。 本文以甲基丙烯酸与十八醇采用直接酯化法合成了甲基丙烯酸十八酯，试验中探讨了原料摩尔配比、反应温度、反应时间对酯化反应的影响。并确定了最适宜反应条件为：甲基丙烯酸与十八醇的摩尔比为3:1，w(对甲苯磺酸)为1.2%，w(对苯二酚)为0.7%，回流条件下逐步升温反应4h，携水剂w(甲苯)为30%。通过IR对合成的单体甲基丙烯酸十八酯的结构进行了表征。 以甲基丙烯酸十八酯、苯乙烯、丙烯酰胺为单体采用溶液聚合法合成油溶性多元共聚物降粘剂，在实验中探讨了反应物的配比、引发剂用量、反应时间、反应温度以及降粘剂加入量等对产物降粘性能的影响，确定适宜条件：甲基丙烯酸十八酯(A):苯乙烯(S):丙烯酰胺(Z)单体配比为6:2:1，引发剂BPO的用量1.0%，反应时间4h，反应温度75℃。并对降粘剂进行了降粘效果评价，产品具有一定降粘效果，降粘率可达56.6%。 关键词：甲基丙烯酸十八酯；油溶性降粘剂；共聚物 ABSTRACT Heavy oil of high viscosity, high density, mobility than conventional resources are poor, so the viscosity reducing agent research and Discussion on its mechanism has important significance. this paper, with acrylic acid and eighteen alcohol by direct esterification synthesis of methacrylic acid eighteen ester, experiment explored material molar ratio, reaction temperature, reaction time on the esterification reaction of ring effect. And the optimal reaction conditions were: methacrylic acid with eighteen alcohol in the molar ratio of 3:1, w (toluene sulfonic acid)1.2%, w (P )0.7%, a backflow condition gradually warming response to 4h, water carrying agent of w (toluene)30%. Through IR on the synthesis of methacrylic acid eighteen ester monomer characterization. In order to Octadecyl methyl-acrylate, styrene, acrylamide monomer synthesized by solution polymerization of oil soluble copolymer viscosity reducer, in the experiment of reactant ratio, dosage of initiator, reaction time, reaction temperature and the reducing agent amount on product viscosity properties, determine the optimum conditions: methacrylic acid eighteen ester (A):styrene (S):acrylamide(Z) monomer ratio of 6:2:1, the amount of initiator BPO=1%, reaction time 4h, reaction temperature75℃. And the viscosity of viscosity redu