丁基锂引发聚合无规立构聚苯乙烯DSC曲线的比较研究.pdfVIP

5 No . 5 1998 10 ACTA POLYM ERICA SINICA O t. , 1998 快报 DSC* 1, 2 1 1* * 王 松 戴庆平 程 时 1 2 ( 210093 , 100081 ) , DSC , , . DSC T , g [ 1] . 2 6 . ( M n= 10 ~ 10 ) 3 T , 10 DSC g , DSC 3 13 , 10 CNM R [2] . 1 , , [ 3] , . ( SEC) 1[ 4] . Table 1 Mole ular properties, solution spe ifi ations, melting peak temperatures and areas for aPS samples M M / M T 1) [4] * [ 3] * Sample n w n m H H [ ] C C / C 10- 4 ( ) ( J/ g) (J/g) ( mL/ g) ( g/ mL) ( SEC) ( SEC) ( DSC) ( DSC) ( DSC) A 0. 046 1. 25 2. 62 0. 38 0. 05 B 0. 075 1. 15 2. 97 0. 34 0. 06 C 0. 28 1. 04 78. 2 9. 41 11. 76 4. 65 0. 22 0. 07 D 0. 49 1. 04 89. 1 6. 53 9. 83 7. 17 0. 14 0. 1 E 0. 69 1. 04 90. 7 5. 56 8. 68 0. 12 0. 1