溶液法制备的ch3nh3pbi3薄膜的时结构及光学性能-物理电子学专业毕业论文.docxVIP

内蒙古大学硕士学位论文PREPARATION 内蒙古大学硕士学位论文 PREPARATION AND OPTICAL PROPERT皿S OF MAPbl3／MAPbl3啊Cl工 阿IN FILMS ABSTRACT 111 me paSt tIlree yearS，舢唱aIlic-orga血hybrid per0Vsk醅(CH3NH3Pbl3， MA Pbl3)haS been洒Vestigated ennl_us iastically aLs one of me most promisiI培 ma把血ls for li出harvester证solar cell’ma．m眵due to its h磅oVemll cen e箍Ici跚cy， wn cert低d valLleS aS tli曲aS 20．8％，wide Spec砌absoIption姗ge and 10w temperature process． IIl t11is mesis，MAPbl3 th证fihns were prepared on Inesoporous T幻2 elec讯)de、谴h two．s旬印sohnion Inethod．E行．ectS of maill process p龃锄eters on t11e fihIl s仃uct呱e，moIpholo影a11d optical properties were chamcter眈d us堍X_ray di妇眺tion(Ⅺ①)，sc龇血g ek哟n mic∞scop le(sE蚂，e艘哥如perS眈X-ray spec怕scople(EDS)and UVVis mle sp。c仃ophotometer(UV一Ⅶ)． Us血g the仃aditioml spm coat证g—d币p吨nlethod，MAPbl3恤films、Ⅳere prep删by却p吨me precursor日雠of Pbl2 m me isoprop趾ol solution of CH3NH3I(M触)at d惭ent tempemtures．It was found mat wicllⅡ1e mrease of temp咖，也e胁sfoⅡl：lation of Pbl2证她MAPbl3啪s pmmoted and也e s协of panic les and surfke coVerage of thin filIIls were inproVed．When the djpp访g lI 万方数据 内蒙古大学硕士学位论文temperature 内蒙古大学硕士学位论文 temperature raiSe to 45 C，Ⅱle nliIl：fihIl has been舰nSf0册ed i11to MAPbl3 coHpletely，w孙the best s比face coVe蹿and light absorption．The particle s玩， s ur：‰e coVemge and abso印tion propeI如s were a脓cted aS temp耐ure fⅦner iIlcreased． In order to而proVe t11e properties oftIle tll证fi】IIls，Ⅱle converSion舶m廿le Pbl2 t0 MAPbl3 is accompljshed by Spin coating an upper hyer of MAI on t：he precursor句m followed by aImealing at a h适h temperat、】re．The resuh show也at qualined filIlls could be obta证ed、)v11en锄ealed at 110。C．hlcreaS缸培nle cycles of s曲co妇g call pro盯∞te me们Ilsfo咖a：tion Pbl2缸o№廿b13趾d me sulface cov哪ge of me th访fihn．Compa瑚wim脚b13，MAPbl3#k t11i11 fihns p印ared by seVeral spjIl-coatiI培Hletllod show la唱er gra缸lS w“h c01unmar s协lcture，unifo肌 s疵e aIld s仃0ng light a：bsoIption propeny． KEⅥⅣORDS：Perovsl(ice soJar cell；1Ⅶo—st印m劬od；CH3NI七Pbl3恤filIIl； 0ptical prope啊 I¨ 万方数据 内蒙古大学硕士学位论文目录 内蒙古大学硕士学位论文 目录 第一章绪论 I