固相反应制备PtC催化剂和其对甲醇电催化氧化.PDFVIP

3 4 ( ) Vol. 3 No. 4 2003 JOURNAL OF NANJING NORMAL UNIVERSITY( ENGINEERING AND TECHNOLOGY) 2003 固相反应制备Pt/ C 催化剂及其 对甲醇的电催化氧化 1 1 1 1 2 1,2 唐亚文 , 杨辉, 周益明, 李钢 , 邢巍 , 陆天虹 ( 1. , 210097, ) ( 2. , 130022, ) [ ] Pt 20% Pt/ C , X E-TEK Pt/ CPt/ C. : Pt/ C, Pt 31 8 nm 815 nm; , Pt/ C , E-TEK Pt/ C , Pt/ C. [ ] , , , Pt/ C [ ] TM911.4, [ ] B, [ ] 1 72- 1292- ( 2003) 04- 000 - 05 0 引言 [ 1] , . ( DMFC) , [ 2] . ,DMFC Pt , , Pt [ 3, 4] DMFC . Pt , Pt , , ; , Pt , . [ 5] [ ] [ 7] Pt ( liquid phase reaction, LPR) . , Pt . ( solid phase reaction, SPR) , Pt/ C , X ( XRD) (TEM) E-TEK Pt/ C Pt/ C . 1 实验部分 111 , , 3 . XRD : 2003- 0 - 03. : / 0 (G200002 408) / 0( 2001AA3230 0) ( ( BQ2000009) ( JH02) 080) . : , 1970- , , . : , 1943- , , , . ) ) , : Pt/ C D/ max-rC X , 40 kV, 100 mA, CuK . TEM A TEM-200CX , 200 kV. CHI CHI 00 . 112 11211 固相反应法制备Pt/ C 催化剂 80 mg Vulcan XC-72 , 21 mL 01038 mol/L H PtCl NaOH 2 , , 10 min. 55 e , , , . , , , 90 e , Pt 20% Pt/ C . 11212 液相反应法制备Pt/ C 催化剂 [ 5] NaBH4 . 80 mg Vulcan XC-72 40 mL 21 mL 01038 mol/ L H2 PtCl , 5 mL 0125 mol/ L NaBH4 , 1min 4 mL mol/ L HCl NaBH4 , , , 90 e , Pt