《固体超强酸SO42-TiO2Fe2O3的光催化降解含酚废水》-毕业论文.DOCVIP

PAGE 毕 业 论 文 作 者： 学 号： 0704130114 院 系： 化学工程学院 专 业： 应用化学 题 目：固体超强酸SO42-/TiO2/Fe2O3的光催化降解含酚废水 指导者： 讲师 2011 年 6 月 吉 林 摘 要 PAGE IV 固体超强酸SO42-/TiO2/Fe2O3的光催化降解含酚废水 摘 要 本文通过制备固体超强酸SO42-/TiO2/Fe2O3为基础，以废水中的苯酚作为研究对象，采用4-氨基安替比林紫外分光光度法作为分析方法，研究SO42-/TiO2/Fe2O3光催化降解苯酚的特性，探讨了影响SO42-/TiO2/Fe2O3光催化降解水中苯酚的因素。并且测出了在不同温度下制备的固体超强酸对水中苯酚的影响。主要结论如下：影响影响SO42-/TiO2/Fe2O3光催化降解苯酚行为的因素主要有苯酚溶液初始浓度、光照因素、溶液pH值、反应时间、催化剂投加量等。苯酚初始浓度越高，降解率越低;紫外光源效果最好，相同条件下光距越小苯酚降解率越高，有效水深越小苯酚降解率越高;苯酚降解率受溶液pH值的影响较大，整体酸性条件下降解率比碱性体条件要高;苯酚降解率随反应时间的延长越来越高，刚开始降解率升高较快，最后趋于平缓;苯酚降解率随着催化剂SO42-/TiO2/Fe2O3投加量的增加而增高，开始阶段降解率增加较快，最后保持稳定。 关键词：SO42-/TiO2/Fe2O3 ，光催化降解，含酚废水 Abstract Solid super acid SO42-/ TiO2 / Fe2O3 light catalytic degradation of hydroxybenzene wastewater Abstract This article through the preparation of solid super acid SO42-/ TiO2 / Fe2O3 to study the waste water of phenol, The method of spectrophotometry in 4-Aminor -AntiPyrine was used to analysis sephenol in this study. the SO42-/ TiO2 / Fe2O3 photocatalytic degradation of characteristics, discusses the influence SO42-/ TiO2 / Fe2O3 photocatalytic degradation of the water of the factors. The main conclusions are as follows: affected SO42-/ TiO2 / Fe2O3 photocatalytic degradation of phenol behavior are the major factors of the initial concentration of the solution, illumination factors, pH value, solution reaction time, catalyst dosing quantity, etc. The UV light source, the best effect under the same conditions from the smaller light of the degradation rate is high, the less effective water depth of the higher the degradation rate; the overall decline than the alkaline solution rate higher body condition; The degradation rate of reaction time with the extension of more and more high, just start degradation rate increases quickly, finally tend to gently; Phenol as catalyst degradation ate