摘要摘要镧锶钴氧化物钙钛矿晶相常应用於气体感测铁电记忆材料.DOC

[ 摘要 ] 摘 要鑭鍶鈷氧化物鈣鈦礦晶相常應用於氣體感測；鐵電記憶材料；高溫燃料電池的電極。合成高化學組成之奈米鑭鍶鈷氧化物為學者之重要研究課題。本研究以檸檬酸/乙二醇為配位劑，經聚酯化反應成溶膠(Sol)，經膠化後形成三度空間網狀聚合物之凝膠(Gel)，再由旋轉塗佈法於(100)矽基板上，製備 (La0.8,Sr0.2)CoO3薄膜。利用FTIR, TGA/DTA, SEM和XRD等設備探討檸檬酸/金屬離子和乙二醇/檸檬酸莫耳比，對生成(La0.8,Sr0.2)CoO3(LSCO)粉末性質的影響，且由前導物轉換為鈣鈦礦陶瓷的反應機制。此外生成薄膜的結晶構造，微結構性質和薄膜的表面形態亦一併研究。研究結果顯示：在乙二醇/檸檬酸的莫耳比為2時，於500℃可生成鈣鈦礦結構粉末。在乙二醇/檸檬酸的莫耳比為2-3時，鈣鈦礦結構的生成溫度低於500℃，但需於700℃下煆燒才可生成高純度的LSCO奈米粉末粉末顆粒大小約50-60nm。以乙二醇/檸檬酸莫耳比為2所得的溶膠製得的LSCO薄膜，膠化時間愈久，溶膠的聚合度提升，使膜面較為平整，但隨膠化時間太久，黏度太大，造成表面塗佈不均。退火溫度上升，可使薄膜緻密化，且降低膜厚。鑭鍶鈷薄膜可於500℃下製得到。在600℃所得之LSCO 鈣鈦礦薄膜，由AFM分析，薄膜表面的相對粗糙度為Rm=367.13nm)。 [ 英文摘要 ] Perovskite structured conductive oxides ABO3, such as SrRuO3, LaNiO3 and La1-xSrxCoO3 attracted a lot of attention in recent years due to a number of applications. Particularly, La1-xSrxCoO3 (LSCO) used in gas sensors, oxygen catalyst and ferroelectric random access memories were studied wildly by scholars.Solid solution La1-xSrxCoO3, with emphasis on La0.8Sr0.2CoO3, was prepared from the resins synthesized by the polymerization of citric acid and ethylene glycol. The synthesis procedure was optimized by systematically varying molar ratios of citric acid/metal ions (RM), ethylene glycol/citric acid (RG) and calcinations temperature. The resulting effects on sol and powder properties was studied using thermogravimetric analysis/different scanning calorimetry (TGA/DTA), Fourier transform infrared spectroscopy(FTIR), and X-ray diffraction (XRD). The results indicated that the molar ratio of citric acid/metal ions at 3, the nanometric-sized LSCO perovskite powdercan be synthesized at temperature as low as 500°C. Similarly, the molar ratio of ethylene glycol/citric acid at 2-3, the LSCO powder can also be obtained at 500 oC, and exhibited a pure phase of perovskite had a particle size of about 90-110 nm as calcined at 700 oC. The thin film was produced from the sol, obtained from the molar ratio of ethylene glycol/citric acid at 2, spin-coating on Si (100) substrate. The longer the gel