纳米片状P沸石的合成及其结构特征-硅酸盐学报.PDF

第 46 卷第 5 期 硅 酸 盐 学 报 Vol. 46 ，No. 5 2 0 1 8 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY May ，2018 DOI ：10.14062/j.issn.0454-5648.2018.05.16 纳米片状P 沸石的合成及其结构特征 高禾鑫，李 鹏，李 彪，刘芝平，郑家军，孔庆岚，潘 梦，李瑞丰 (太原理工大学，能源化工与催化研究中心，太原 030024) 摘 要：以超稳Y 沸石(FSY)为前驱体，在水热合成体系中制备出了纳米片状 P 沸石，讨论了片状 P 沸石形成的影响因素， 并对制备的材料进行了表征。结果表明：合成片状 P 沸石厚度为 20~50 nm，直径约为 500 nm，在P 沸石中引入了 2~80 nm 的多级孔结构，其介孔孔容为 0.12 cm3/g 。合成的 P 沸石硅铝比(Si/Al)为 2.6~3.2 ，且随晶化时间的延长，P 沸石的硅铝比(Si/Al) 呈现下降的趋势，受 FSY 沸石解聚的控制。Ca2+交换表明，随着交换次数的增加，交换度逐渐提高。 关键词：纳米；片状；P 沸石；多级孔；水热法 中图分类号：TQ426 文献标志码：A 文章编号：0454–5648(2018)05–0723–08 网络出版时间：2018–03–12 Synthesis and Structure Characteristics of P Zeolite Nano-flakes GAO Hexin, LI Peng, LI Biao, LIU Zhiping, ZHENG Jiajun, KONG Qinglan, PANMeng, LI Ruifeng (Research Centre of Energy Chemical Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024, China) Abstract: P zeolite nano-flakes were synthesized by using ultrastable Y zeolite(FSY) as a partial nutrient via a facile template-free hydrothermal route. The factors affecting the formation of nano-flakes of P zeolite crystals were discussed, and the as-synthesized samples were characterized. The results revealed that the as-synthesized samples were nano-flakes of P zeolite crystals with the thickness of 20–50 nm and the diameter of approximately 500 nm. A hierarchical porosity system ranged from 2 to 80 nm in the as-synthesized zeolite sample was created, which ascribed to the accumulation of nano-flakes of P zeolite crystals, and the mesoporous volume was 0.12 cm3/g.The Si/Al ratios of the as-synthesized P zeolite samples were between 2.6