壳聚糖固体聚合物电池用膜3.PDF

第 19 卷 第 4 期 化　学　进　展 Vol. 19 No. 4 2007 年 4 月 PROGRESS IN CHEMISTRY 　Apr. , 2007 壳聚糖固体聚合物电池用膜 崔　铮　相　艳 　张　涛 (北京航空航天大学材料科学与工程学院 　北京 100083) 摘 　要 　壳聚糖是甲壳素脱乙酰基的产物 ,具有良好的成膜性、生物相容性、环保以及价格低廉等特点。 作为一种碱性高分子膜材料 ,近年来已成为聚电解质研究领域中的研究热点。本文综述了壳聚糖固体聚合 物电池用膜的研究现状 ,其改性工艺主要包括共混、化学改性、质子酸掺杂、无机盐掺杂等方法 , 比较了各种 工艺处理后壳聚糖固体聚合物电解质膜的性能差异 ,并就壳聚糖固体聚合物电解质膜中离子传导机理中有 待解决的问题进行探讨 ,并提出了进一步改进壳聚糖固体聚合物电解质膜性能的研究思路。 关键词 　壳聚糖膜 　改性 　聚电解质 　燃料电池 　电导率 ( ) 中图分类号: O636 ; TM9114 　文献标识码 : A 　文章编号 : 1005281X 2007 ChitosanBased Solid Polyelectrolyte Membranes for Cell Application Cui Zheng 　Xiang Yan 　Zhang Tao ( ) School of Material Science and Technology , Beijing University of Aeronautics and Astronautics , Beijing 100083 , China Abstract 　Chitosan ( Nacetylated chitin) is an alkaline polymer membrane material which is biocompatible , nontoxic , natural , environmentally friendly , and low cost. It has been widely studied for use as a polyelectrolyte material. This paper reviews the applications of chitosanbased solid polyelectrolyte membranes in fuel cells. Methods for preparing chitosan membranes are discussed which include blending , chemical derivatization , and doping with proton acids or inorganic salts. The effects of these modifications on the performance of various chitosanbased membranes are described. Some unsolved problems in proton conductivity mechanism studies are mentioned. Some directions for future research on chitosanbased membranes as