基于bi2o3异质结光催化剂制备、表征及催化活性研究-化工过程机械专业论文.docxVIP

万方数据 万方数据 crystalline structure and light absorption performance of Bi2O3 was mainly affected by the calcination temperature. When the calcination temperature was 350℃ and the calcination time was 4h, the as-synthesized N-doped β-Bi2O3 had the best activity. For α-Bi2O3, when the calcination temperature and time were 450℃ and 4h, respectively, the obtained α-Bi2O3 had the best activity. NaBiO3/Bi2O3 could be obtained by oxidizing α-Bi2O3 under alkaline condition. There was not much difference among the light absorption performances of all the NaBiO3/Bi2O3 samples, but the separation efficiency of electrons and holes first increased and then decreased with the content of NaBiO3 increasing. The separation efficiency of electrons and holes in 5.72% NaBiO3/Bi2O3 was the highest, which contributed to its best activity. Bi5O7I/Bi2O3 could be prepared by chemical etching of α-Bi2O3 by HI. It is found that coupling of Bi5O7I could make the absorption of Bi2O3 shift from 447nm to more than 600nm. However, if the content of Bi5O7I was not high enough, the recombination possibility of electrons and holes in Bi5O7I/Bi2O3 heterojunction-structured photocatalyst was even larger than pure Bi2O3, only when the content of Bi5O7I reached to 80.48%, the recombination of electrons and holes reduced. In short, coupling of Bi2O3 with NaBiO3 or Bi5O7I can not only provide reference for studies of photocatalysts containing Bi, but also provide an effective technique for degradation of organic pollutants. KEYWORDS: Photocatalysis; Visble Light; Bi2O3; NaBiO3; Bi5O7I 目录 HYPERLINK \l _bookmark0 第一章 绪论..................................................................................................................1 HYPERLINK \l _bookmark1 1.1 半导体光催化简介..........................................................................................1 HYPERLINK \l _bookmark2 1.2 Bi2O3 光催化机理 1 HYPERLINK \l _bookmark3 1.3 Bi2O3 晶型结构 3 HYPERLINK \l _bookmark4 1.4 Bi2O3 制备方法 3 HYPERLIN