基于aot表面活性剂反相微乳液体系电导行为的研究-应用化学专业论文.docxVIP

基于 基于 AOT 表面活性剂反相微乳液体系电导行为的研究 河北工业大学硕士学位论文 河北工业大学硕士学位论文 INVESTIGATION ON CONDUCTIVITY BEHAVIOR OF AOT REVERSE MICROEMULSION ABSTRACT Microemulsion that consist of surfactants, cosurfactant, oil and water at a certain percentage is a thermodynamic stable system with the particle radius of 10~200nm. Its interfacial tension is very low. Alkanol is often used directly as a solvent or reaction medium, thus it was important to study the behavior of the surfactant in the alcohol oil. The conductivity behaviors of water-in-toluene-alkanol (heptanol,decanol) reverse microemulsions stabilized by AOT with and without the additives (sodium chloride, sodium salicylate and sodium cholate) were investigated by the conductance measurements. The effect of temperature on the conductance were also studied. This paper also studied the effect of different alkanol and nonionic surfactant (Brij-56, TX-100, Tween80, Spans) on conductance behavior of water /AOT/IPM/alkanol systems, and the droplets size were measured through dynamic light scattering (DLS). The results are as follows: The percolation phenomenon was apparently resisted by toluene in the water/AOT/decanol system, while no effect in the water/AOT/heptanol system. The different effects of additives on the conductivity behavior were observed and discussed. The conductance of water/AOT/heptanol/toulene system had a hardly change in the present of sodium chloride and sodium salicylate, and it decreased with the increase of sodium cholate concentration. The conductance of water/AOT/decanol/toulene system increased with the increase of sodium cholate and sodium salicylate concentration, and it changed a little with the concentration of sodium chloride. No percolation threshold induced by temperature was detected either in the absence or in the presence of additives in the 5~40°C. There were different effect of alcohol (ethanol, propanol, butanol, pentanol) on the conductane of water/AOT/IPM/alkanol systems. The results showed that t